書誌事項
- タイトル別名
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- Fabrication and Mechanical Properties of Cr, V Doped Mo<sub>2</sub>NiB<sub>2</sub> Hard Materials Based on Crystallographic Approaches
- 結晶学的知見に基づくCr,V添加Mo₂NiB₂系超硬材料の作製と機械的特性
- ケッショウガクテキ チケン ニ モトズク Cr,V テンカ Mo ₂ NiB ₂ ケイ チョウコウザイリョウ ノ サクセイ ト キカイテキ トクセイ
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<p>The effects of Cr or V substitution on the crystal structure and mechanical properties of Mo2NiB2 were investigated by experiments and first principles calculation. Mo2Ni1-xCrxB2 and Mo2Ni1-xVxB2 samples were synthesized via the powder metallurgy method. The XRD analysis revealed that the tetragonal Mo2NiB2 phase appeared with the addition of the Cr or V in both Mo2Ni1-xCrxB2 and Mo2Ni1-xVxB2 samples, and increased with the increase of the Cr or V content x. Orthorhombic Mo2NiB2 phase decreased with the increase of the Cr or V content x, and completely disappeared at x = 0.75. The Vickers hardness of Mo2Ni1-xCrxB2 and Mo2Ni1-xVxB2 samples improved with increasing Cr or V additions, and the maximum values of 20.4 GPa and 19.8 GPa for x = 0.75 samples, respectively. The calculated shear modulus of the tetragonal Mo2Ni1-xCrxB2 and tetragonal Mo2Ni1-xVxB2 increase with increasing Cr or V content x. The calculated Vickers hardness of orthorhombic Mo2NiB2, tetragonal Mo2CrB2 and tetragonal Mo2VB2 are 21.915 GPa, 22.492 GPa and 24.656 GPa, respectively. The Crystal Orbital Hamilton Population (COHP) analysis indicates the excellent mechanical properties of tetragonal Mo2CrB2 and tetragonal Mo2VB2 are due to the strong bonding between Mo-(Cr or V) and (Cr or V)-B atoms.</p>
収録刊行物
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- 粉体および粉末冶金
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粉体および粉末冶金 68 (7), 278-285, 2021-07-15
一般社団法人 粉体粉末冶金協会
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詳細情報 詳細情報について
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- CRID
- 1390570176044127360
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- NII論文ID
- 130008065014
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- NII書誌ID
- AN00222724
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- ISSN
- 18809014
- 05328799
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- NDL書誌ID
- 031615876
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可