Isomerization of Unprotected Aldoses to 2-Deoxyaldonic Acids Induced by Visible Light/Quinuclidine/Water-Soluble Iridium Complex in Water

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  • Yusuke Masuda
    Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510 , Japan
  • Hiromu Tsuda
    Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510 , Japan
  • Masahiro Murakami
    Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510 , Japan

Abstract

<jats:title>Abstract</jats:title> <jats:p>We herein report that a visible light/quinuclidine/water-soluble iridium complex system is highly effective for promoting the isomerization reaction of aldoses to 2-deoxyaldonic acids in water. The product yields and functional group compatibility are much better than those observed with a UV light/water-soluble benzophenone system.</jats:p>

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