Nitrogen-Substitution in the Flapping Wings of Cyclooctatetraene-Fused Molecules

  • Kensuke Suga
    Graduate School of Science, Kyoto University, Kitashirakawa Oiwake, Sakyo, Kyoto 606-8502 , Japan
  • Takuya Yamakado
    Graduate School of Science, Kyoto University, Kitashirakawa Oiwake, Sakyo, Kyoto 606-8502 , Japan
  • Shohei Saito
    Graduate School of Science, Kyoto University, Kitashirakawa Oiwake, Sakyo, Kyoto 606-8502 , Japan

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<jats:title>Abstract</jats:title> <jats:p>New synthetic protocols for nitrogen-embedded flapping molecules have been developed. Gram-scale synthesis of a key precursor, tetraamine of dibenzo[a,e]cyclooctatetraene has been established for designing flapping quinoxaline and flapping phenazineimide. The impact of the nitrogen substitution on the photophysical properties and the viscosity-probing function has been investigated in comparison with the reported flapping anthraceneimide.</jats:p>

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