静水圧分光分析の新潮流：分子から生体細胞の制御に向けて

• 木下 智和

  東京工業大学理学院化学系

• 福原 学

  東京工業大学理学院化学系 JST-さきがけ

書誌事項

タイトル別名

• New Trends in Hydrostatic Pressure Spectroscopy towards from Molecules to Living Cells
• セイスイアツ ブンコウ ブンセキ ノ シン チョウリュウ : ブンシ カラ セイタイ サイボウ ノ セイギョ ニ ムケテ

抄録

Hydrostatic pressure is one of the fundamental and significant external stimuli, and thus, has attracted attention in synthetic chemistry and photo-physical and -chemical processes. In considering weak interaction systems such as biological and supramolecular reactions on the basis of thermodynamics, enthalpy and entropy changes exquisitely keep the balance each other according to the enthalpy-entropy compensation law, meaning that it seems to be difficult to control reactions/rates by only either of these parameters. On the other hand, reaction/activation volume change (ΔV)-based hydorstatic pressure (P) control turns out to be an alternative to the conventional control method. In this review, we wish to report our recent hydrostatic pressure-spectroscopic results on ΔV as solvation, conformational change, molecular recognition, and biological reaction.

収録刊行物

• 高圧力の科学と技術

  高圧力の科学と技術 31 (2), 74-81, 2021

  日本高圧力学会

キーワード

• hydrostatic pressure
• spectroscopy
• conformational change
• solvation
• molecular recognition
• photophysics

詳細情報

• CRID: 1390571395584838400
• NII論文ID: 130008111015
• NII書誌ID: AN10452913
• DOI: 10.4131/jshpreview.31.74
• ISSN: 13481940
• ISSN: 0917639X
• NDL書誌ID: 031822781
• Web Site: http://id.ndl.go.jp/bib/031822781
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I031822781
• Web Site: https://www.jstage.jst.go.jp/article/jshpreview/31/2/31_74/_pdf
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• 抄録ライセンスフラグ: 使用不可