Bonding performance of a thiohydantoin-methacrylate monomer on noble metal alloys

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  • TAKEHANA Kosuke
    Division of Applied Oral Sciences, Nihon University Graduate School of Dentistry
  • KOIZUMI Hiroyasu
    Department of Dental Materials, Nihon University School of Dentistry Division of Biomaterials Science, Dental Research Center, Nihon University School of Dentistry
  • HIRABA Haruto
    Department of Fixed Prosthodontics, Nihon University School of Dentistry Division of Advanced Dental Treatment, Dental Research Center, Nihon University School of Dentistry
  • KODAIRA Akihisa
    Department of Fixed Prosthodontics, Nihon University School of Dentistry Division of Advanced Dental Treatment, Dental Research Center, Nihon University School of Dentistry
  • YONEYAMA Takayuki
    Department of Dental Materials, Nihon University School of Dentistry Division of Biomaterials Science, Dental Research Center, Nihon University School of Dentistry
  • MATSUMURA Hideo
    Department of Fixed Prosthodontics, Nihon University School of Dentistry Division of Advanced Dental Treatment, Dental Research Center, Nihon University School of Dentistry

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<p>This study assessed the effect of a primer containing 10-methacryloyloxydecyl-(2-thiohydantoin-4-yl)propionate (MDTHP) on the bonding of noble metal alloys to an acrylic resin. Three noble metal alloys were selected as adherends, and V-Primer containing 6-(4-vinylbenzyl-n-propyl)amino-1,3,5-triazine-2,4-dithione was used as a comparative control. The disk specimens of each noble metal alloy were wet-ground and divided into three conditions: specimens primed with MDTHP primer or V-Primer, and specimens without priming. An acrylic resin was bonded to each specimen, and the specimens were performed the shear bond test. The MDTHP primer showed higher shear bond strength than the V-Primer for all specimens. X-ray photoelectron spectroscopic analysis showed that MDTHP was adsorbed on the Au-Pt-Pd alloy surface even after acetone cleaning. MDTHP binds not only with Cu but also with Au and Ag, promoting the bond strength of noble metal alloys. The effectiveness of MDTHP on dental noble metal alloys was suggested.</p>

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  • Dental Materials Journal

    Dental Materials Journal 41 (2), 279-285, 2022-03-25

    一般社団法人 日本歯科理工学会

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