Crystal Structure of a Hydrolyzed Product of the Cobalt(III) Complex with 1-(3,5-Dichlorosalicylideneamino)-3-amino-2-propanol

• MIKURIYA Masahiro

  Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Biological and Environmental Sciences, Kwansei Gakuin University

• TSUCHIMOTO Nagisa

  Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Biological and Environmental Sciences, Kwansei Gakuin University

• KOYAMA Yoshiki

  Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Biological and Environmental Sciences, Kwansei Gakuin University

• MITSUHASHI Ryoji

  Institute of Liberal Arts and Science, Kanazawa University

• TSUBOI Motohiro

  Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Biological and Environmental Sciences, Kwansei Gakuin University

Abstract

The crystal structure of a hydrolyzed product of the cobalt(III) complex with 1-(3,5-dichlorosalicylideneamino)-3-amino-2-propanol (H₂dcsalapr) was determined by the single-crystal X-ray diffraction method at 90 K. It crystallizes in the triclinic space group P1 with a = 9.2242(15)Å, b = 9.3391(16) Å, c = 9.5525(16)Å, α = 75.574(3)°, β = 85.550(3)°, γ = 69.154(3)°, V = 744.7(2)ų, D_x = 1.634 g/cm³, and Z = 1. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0489 and 0.1093, respectively, for all 3319 independent reflections. The X-ray structure analysis revealed a centrosymmetric octahedral Co(III) complex with two hydrolyzed Schiff-base ligands, Hdcsalapr⁻, in a facial mode, one chloride ion, two acetonitrile molecules, and two water molecules in the unit cell, which was formed from the reaction solution of cobalt(II) chloride hexahydrate with 1,3-bis(3,5-dichlorosalicylideneamino)-2-propanol in the presence of triethylamine in acetonitrile.

Journal

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 38 (0), 9-11, 2022-01-10

  The Japan Society for Analytical Chemistry

Keywords

• Materials Chemistry
• Analytical Chemistry

Details

• CRID: 1390853719881595904
• NII Article ID: 130008140285
• DOI: 10.2116/xraystruct.38.9
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/38/0/38_9/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed