Association Behavior of a Homopolymer Containing Choline Phosphonate Groups in Aqueous Solutions

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  • Thi Lien Nguyen
    Department of Applied Chemistry, Graduate School of Engineering, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280 , Japan
  • Masaru Mukai
    Institute for Materials Chemistry and Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395 , Japan
  • Daiki Ihara
    Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395 , Japan
  • Atsushi Takahara
    Institute for Materials Chemistry and Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395 , Japan
  • Shin-ichi Yusa
    Department of Applied Chemistry, Graduate School of Engineering, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280 , Japan

抄録

<jats:title>Abstract</jats:title> <jats:p>Poly(2-methacryloyloxyethyl choline methylphosphonate) (PMCP) containing choline phosphonate groups, which consist of quaternary ammonium and anionic phosphonate groups in reverse order to that of phosphorylcholine, was synthesized via controlled radical polymerization. PMCP formed aggregates in water through electrostatic interactions. Meanwhile, poly(2-methacryloyloxyethyl phosphorylcholine) (PMPC) having a similar structure to that of PMCP was dissolved as a unimer in both water and salt solutions.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 51 (2), 103-106, 2021-12-07

    Oxford University Press (OUP)

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