CuCl Microcrystallite-Doped SiO<sub>2</sub> Glass Thin Films Prepared by RF Sputtering

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<jats:p> CuCl microcrystallites were successfully doped into SiO<jats:sub>2</jats:sub> glass thin films by means of the magnetron rf-sputtering technique. A transmission electron microscopy (TEM) measurement showed that the microcrystallites had a spherical configuration. The average size of the microcrystallites was less than 5 nm and it was affected by the preparation condition and postdeposition annealing time. Optical absorption peaks corresponding to Z<jats:sub>3</jats:sub> and Z<jats:sub>1,2</jats:sub> exciton were observed. These absorption lines shifted to a higher-energy side with decreasing microcrystallite size. This phenomenon seems to relate to the quantum size effect. </jats:p>

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