Deep Electronic Levels of Al<sub>x</sub>Ga<sub>1-x</sub>N with a Wide Range of Al Composition Grown by Metal–Organic Vapor Phase Epitaxy

Abstract

<jats:p> Deep electronic levels of Al<jats:sub> <jats:italic>x</jats:italic> </jats:sub>Ga<jats:sub>1-<jats:italic>x</jats:italic> </jats:sub>N (0.25<<jats:italic>x</jats:italic><0.60) were investigated by deep level transient spectroscopy (DLTS) and photocapacitance methods. Si-doped AlGaN layers were grown on an AlN/sapphire template by metal–organic vapor phase epitaxy. DLTS analysis using a sampling time window of up to 100 s showed two dominant deep levels with activation energies (Δ<jats:italic>E</jats:italic>) higher than 1.0 eV in Al<jats:sub> <jats:italic>x</jats:italic> </jats:sub>Ga<jats:sub>1-<jats:italic>x</jats:italic> </jats:sub>N with <jats:italic>x</jats:italic>=0.25 and 0.37. The densities of those levels were higher than 1×10<jats:sup>16</jats:sup> cm<jats:sup>-3</jats:sup>. For the Al<jats:sub>0.60</jats:sub>Ga<jats:sub>0.40</jats:sub>N sample, the deeper levels (Δ<jats:italic>E</jats:italic>>1.5 eV) were detected by photocapacitance measurement. It was found that the energy position of the dominant deep level closely followed the Fermi level stabilization energy reported by Walukiewicz <jats:italic>et al.</jats:italic> [J. Cryst. Growth 269 (2004) 119], indicating that the origin of the dominant deep level in AlGaN is related to a defect complex including anti-site defects and divacancies. </jats:p>

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