Combinatorial Investigation of ZrO<sub>2</sub>-Based Dielectric Materials for Dynamic Random-Access Memory Capacitors

Abstract

<jats:p> We investigated zirconia (ZrO<jats:sub>2</jats:sub>)-based material libraries in search of new dielectric materials for dynamic random-access memory (DRAM) by combinatorial-pulsed laser deposition (combi-PLD). We found that the substitution of yttrium (Y) to Zr sites in the ZrO<jats:sub>2</jats:sub> system suppressed the leakage current effectively. The metal–insulator–metal (MIM) capacitor property of this system showed a leakage current density of less than 5×10<jats:sup>-7</jats:sup> A/cm<jats:sup>2</jats:sup> and the dielectric constant was 20. Moreover, the addition of titanium (Ti) or tantalum (Ta) to this system caused the dielectric constant to increase to ∼25 within the allowed leakage level of 5×10<jats:sup>-7</jats:sup> A/cm<jats:sup>2</jats:sup>. Therefore, Zr–Y–Ti–O and Zr–Y–Ta–O systems have good potentials for use as new materials with high dielectric constants of DRAM capacitors instead of silicon dioxides (SiO<jats:sub>2</jats:sub>). </jats:p>

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