Nuclear Magnetic Resonance and X-Ray Studies of Potassium Ferrocyanide Trihydrate Crystal

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  • Kiriyama Ryôiti
    Institute of Scientific and Industrial Research, Osaka University
  • Kiriyama Hideko
    Institute of Scientific and Industrial Research, Osaka University
  • Wada Takeo
    Institute of Scientific and Industrial Research, Osaka University
  • Niizeki Nobukazu
    Dielectric Materials Research Section, Electrical Communication Laboratory, Nippon Telegraph and Telephone Public Corporation
  • Hirabayashi Hisao
    Dielectric Materials Research Section, Electrical Communication Laboratory, Nippon Telegraph and Telephone Public Corporation

抄録

The atomic coordinates of one previously unknown water oxygen in potassium ferrocyanide trihydrate are determined by X-ray structure analysis in the paraelectric phase at room temperature. In K4Fe(CN)6·3H2O and its isomorphous K4Ru(CN)6·3H2O proton magnetic resonance patterns start to narrow at about −140°C, and definite change in both spectra occurs in the same temperature region around −40°C, about twenty degrees below the respective Curie points. Angular dependence of peak separations has been measured at liquid nitrogen temperature where all water molecules are effectively rigid. Direction angles of three proton-proton vectors with respect to the crystallographic a, b and c axes are, respectively, α0=134°, β0=49°, γ0=73°; α0=90°, β0=90°, γ0=0° and α0=0°, β0=90°, γ0=90°. A possible molecular mechanism for the ferroelectric origin is discussed.

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