Superconductivity at 14.2K in Layered Organics under Extreme Pressure.

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Abstract

We demonstrate that an organic Mott insulator, β′-(BEDT-TTF)2ICl2, is metallized by application of extremely high pressure by means of the cubic anvil press. When the metallic state is stabilized, superconductivity with the highest transition-temperature (Tc) among the organic systems appears. The lower limit of the pressure at which the superconducting transition manifests itself is approximately 7.0 GPa and Tc reaches a maximum value, 14.2 K (onset), at 8.2 GPa. The pressure-temperature phase diagram is constructed and discussed in terms of the comparison with those of other organic systems.

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