Pressure-induced Crossover from Variable Range Hopping to Electron–Electron Interaction in the Organic Conductor (DOET)<sub>2</sub>BF<sub>4</sub>

  • Yasuzuka Syuma
    Department of Material Science, Graduate School of Science, Osaka City University
  • Murata Keizo
    Department of Material Science, Graduate School of Science, Osaka City University
  • Shimotori Masahiro
    Department of Material Science, Graduate School of Science, Osaka City University
  • Fujimoto Tsutomu
    Department of Material Science, Graduate School of Science, Osaka City University
  • Yamada Jun-ichi
    Department of Material Science, Graduate School of Material Science, University of Hyogo
  • Kikuchi Koichi
    Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University

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  • Pressure-induced Crossover from Variable Range Hopping to Electron–Electron Interaction in the Organic Conductor (DOET)2BF4

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This paper reports the pressure effect on resistivity in the quasi two-dimensional (2D) organic conductor (DOET)2BF4 with orientational disorder of BF4 anions. At ambient pressure, the resistivity shows metal–insulator transition at 80 K and 2D variable range hopping (VRH) conduction below 80 K. The insulating behavior is suppressed by applying pressure and the temperature dependence of the resistivity shows the crossover from the 2D VRH to the logarithmic divergence as applied pressure increases. From the observation of the positive magnetoresistance, the logarithmic divergence of the resistivity is not attributed to the Anderson localization, but to the effect of the electron–electron interaction. This crossover is simply understood in terms of the screening effect on the random potential by increase of bandwidth due to applied pressure. It is found that a value of sheet conductance at low temperatures above 8 kbar, where the insulating state is almost suppressed, approaches to the minimum conductivity for a metallic state, σmin=e2h=1⁄(25.8kΩ), first proposed by Mott.

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