Possible Frustration Effects on a New Antiferromagnetic Compound Ce<sub>6</sub>Pd<sub>13</sub>Zn<sub>4</sub> with the Octahedral Ce Sublattice

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  • Possible Frustration Effects on a New Antiferromagnetic Compound Ce6Pd13Zn4 with the Octahedral Ce Sublattice

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Magnetization, specific heat, and electrical resistivity measurements have been performed on polycrystalline samples of a new cubic compound, Ce6Pd13Zn4. This compound exhibits metallic behavior and is classified as a Kondo-lattice system. The trivalent Ce ions are responsible for the antiferromagnetic transition at T-N = 3.3 K and the phase transition at T-N' = 1.3 K with the formation of superzone gaps. The increase in magnetic susceptibilities below T-N and the considerably large value of the specific heat divided by temperature (1.25 J.Ce-mol(-1).K-2) imply the existence of non-ordered Ce magnetic moments due to the geometrical frustration on the octahedral Ce sublattice.

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