Annealing of an AlN buffer layer in N<sub>2</sub>–CO for growth of a high-quality AlN film on sapphire

Abstract

<jats:title>Abstract</jats:title> <jats:p>The annealing of an AlN buffer layer in a carbon-saturated N<jats:sub>2</jats:sub>–CO gas on a sapphire substrate was investigated. The crystal quality of the buffer layer was significantly improved by annealing at 1650–1700 °C. An AlN buffer layer with a thickness of 300 nm was grown by metalorganic vapor phase epitaxy (MOVPE), and was annealed at 1700 °C for 1 h. We fabricated a 2-µm-thick AlN layer on the annealed AlN buffer layer by MOVPE. The full widths at half maximum of the (0002)- and (<jats:inline-formula> <jats:tex-math><?CDATA $10\bar{1}2$?></jats:tex-math> <jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="AP150907if001.gif" xlink:type="simple" /> </jats:inline-formula>)-plane X-ray rocking curves were 16 and 154 arcsec, respectively, and the threading dislocation density was 4.7 × 10<jats:sup>8</jats:sup> cm<jats:sup>−2</jats:sup>.</jats:p>

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