Epitaxial growth of hexagonal tungsten bronze Cs<sub>x</sub>WO<sub>3</sub> films in superconducting phase region exceeding bulk limit

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<jats:title>Abstract</jats:title> <jats:p>We report epitaxial synthesis of superconducting Cs<jats:italic> <jats:sub>x</jats:sub> </jats:italic>WO<jats:sub>3</jats:sub> (<jats:italic>x</jats:italic> = 0.11, 0.20, and 0.31) films on Y-stabilized ZrO<jats:sub>2</jats:sub> (111) substrates. The hexagonal crystal structure was verified not only for the composition within the stable region of the bulk (<jats:italic>x</jats:italic> = 0.20 and 0.31), but also for the out-of-range composition (<jats:italic>x</jats:italic> = 0.11). The onset of the superconducting transition was recorded at 5.8 K for <jats:italic>x</jats:italic> = 0.11. We found a strong correlation between the superconducting transition temperature (<jats:italic>T</jats:italic> <jats:sub>C</jats:sub>) and the <jats:italic>c</jats:italic>-axis length, irrespective of the Cs content. These results indicated that the hidden superconducting phase region of hexagonal tungsten bronze is accessible using epitaxial synthesis of lightly doped films.</jats:p>

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