High Amount Cluster Incorporation in Initial Si Film Deposition by SiH<sub>4</sub> Plasma Chemical Vapor Deposition

Abstract

<jats:p> We have carried out in-situ measurements of Si cluster volume fraction in Si films during plasma chemical vapor deposition by using quartz crystal microbalances (QCM's) together with a cluster-eliminating filter. The cluster volume fraction in films is deduced from film deposition rates with and without Si clusters using QCM's. By employing this method we have revealed a depth profile of the Si cluster volume fraction. A high cluster volume fraction is observed in the initial phase of film deposition. This behavior is compared with time evolution of SiH<jats:sup>*</jats:sup>, Si<jats:sup>*</jats:sup> emission intensities and their intensity ratio. </jats:p>

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