Measurements of Nonlinear Dielectric Constants of Pb(Zr,Ti)O<sub>3</sub> Thin Films Using a Dynamic Measuring Method

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<jats:p> The nonlinear dielectric constants of Pb(Zr,Ti)O<jats:sub>3</jats:sub> (PZT) thin films were studied using a dynamic measuring method. The 111-oriented PZT thin films with various Zr/Ti ratios were deposited on platinum-coated silicon substrates using a sol–gel method. The ε<jats:sub>333</jats:sub> of the films increased with the Zr concentration in the tetragonal region and reached a maximum value of 280 aF/V close to the morphotropic phase boundary (Zr/Ti= 52/48). This measured value is 400 times larger than that of LiTaO<jats:sub>3</jats:sub> single crystals. </jats:p>

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