Growth and Characterization of Ca<sub>2</sub>Al<sub>2</sub>SiO<sub>7</sub> Piezoelectric Single Crystals for High-Temperature Sensor Applications

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<jats:p> The electrical properties of a piezoelectric single crystal of calcium aluminate silicate Ca<jats:sub>2</jats:sub>Al<jats:sub>2</jats:sub>SiO<jats:sub>7</jats:sub> (CAS) were studied at elevated temperatures and its applicability to high-temperature pressure sensors was investigated. The CAS bulk single crystal was grown by the Czochralski method. The piezoelectric <jats:italic>d</jats:italic> <jats:sub>14</jats:sub> and <jats:italic>d</jats:italic> <jats:sub>36</jats:sub> constants were respectively evaluated as 6.04 and 4.04 pC/N by the resonance and antiresonance method. The temperature dependence of the piezoelectric constant was investigated at temperatures up to 500 °C. The electrical resistivity at 800 °C was on the order of 10<jats:sup>8</jats:sup> Ω·cm along both the crystallographic <jats:italic>a</jats:italic>- and <jats:italic>c</jats:italic>-axes. The measurement of direct piezoelectric response at 700 °C demonstrated that the CAS crystal could detect a pseudo-combustion pressure change of an automobile engine. Our observations suggest that CAS crystals are superior candidates for sensing pressure at high temperatures. </jats:p>

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