Small device-to-device variation of 6,13-bis(triisopropylsilylethynyl)pentacene field-effect transistor arrays fabricated by a flow-coating method

Abstract

<jats:p>Bottom-contact/bottom-gate-type organic field-effect transistor (OFET) arrays have been fabricated using a flow-coating method, and the device-to-device variation has been examined. The flow-coated active layer of 6,13-bis(triisopropylsilylethynyl)pentacene (TIPS-PEN) was composed of arrays of needle-shaped crystals whose long axes were aligned along the flow-coating direction. By measuring the electrical characteristics of one hundred twenty OFETs with the channel current direction <jats:italic>parallel</jats:italic> or <jats:italic>perpendicular</jats:italic> to the flow-coating direction, we evaluated the device-to-device variation in the device properties. The field-effect hole mobilites (average ± standard deviation) for the <jats:italic>parallel</jats:italic> and <jats:italic>perpendicular</jats:italic> OFET sets were 0.51 ± 0.03 and 0.12 ± 0.03 cm<jats:sup>2</jats:sup>·V<jats:sup>−1</jats:sup>·s<jats:sup>−1</jats:sup>, respectively. The small standard deviations clearly show the high spatial uniformity of the TIPS-PEN active layer. The much smaller relative standard deviation, a measure of device-to-device variation, for the <jats:italic>parallel</jats:italic> OFET set (6%) can be attributed to a high degree of alignment of needle-shaped TIPS-PEN crystals along the flow-coating direction.</jats:p>

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