Control of Al<sub>2</sub>O<sub>3</sub>/InAlN interface by two-step atomic layer deposition combined with high-temperature annealing

Abstract

<jats:p>An attempt was made to control the Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>/InAlN interface by the phase change of the Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> layer formed by atomic layer deposition (ALD). The electrical properties of an InAlN metal–oxide–semiconductor (MOS) diode with a sufficiently thick ALD-Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> layer deteriorated following conventional postdeposition annealing (PDA) at 850 °C, which is sufficiently high for microcrystallization of the ALD-Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> layer. However, X-ray photoelectron spectroscopy showed no evidence of an interface disorder in the ultrathin ALD-Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>/InAlN structure annealed at 850 °C. Two-step ALD interrupted by annealing at 850 °C right after the formation of the initial ultrathin Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> layer improved the electrical properties of the MOS diode with reduced interface state density (<jats:italic>D</jats:italic> <jats:sub>it</jats:sub>) and leakage current. A weak crystallization of the ultrathin Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> layer was confirmed by transmission electron microscopy. Improvement of the interface disorder by high-temperature annealing is discussed as the origin of the <jats:italic>D</jats:italic> <jats:sub>it</jats:sub> reduction.</jats:p>

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