Single crystalline growth of a soluble organic semiconductor in a parallel aligned liquid crystal solvent using rubbing-treated polyimide films

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<jats:title>Abstract</jats:title> <jats:p>For directional control of organic single crystals, we propose a crystal growth method using liquid crystal as the solvent. In this study, we examined the formation of 2,7-dioctyl[1]benzothieno[3,2-<jats:italic>b</jats:italic>][1]benzothiophene (C<jats:sub>8</jats:sub>-BTBT) single crystals using a parallel aligned liquid crystal (LC) cell and rubbing-treated polyimide films in order to clarify the effects of LC alignment on anisotropic C<jats:sub>8</jats:sub>-BTBT crystal growth. Based on the results, we found that the crystal growth direction of C<jats:sub>8</jats:sub>-BTBT single crystals was related to the direction of the aligned LC molecules because of rubbing treatment. Moreover, by optical evaluation, we found that the C<jats:sub>8</jats:sub>-BTBT single crystals have a aligned molecular structure.</jats:p>

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