Catalyzed Addition of Aldehydes to Activated Double Bonds—A New Synthetic Approach
抄録
<jats:title>Abstract</jats:title><jats:p>In the presence of cyanide ions as catalyst, aromatic and heterocyclic aldehydes can be smoothly added to α,β‐unsaturated ketones, esters, and nitriles in aprotic solvents to form γ‐diketones, 4‐oxo carboxylic esters, and 4‐oxo nitriles. Thiazolium salts in the presence of bases are also suitable catalysts; they permit not only addition of aromatic and heterocyclic aldehydes but also the addition of aliphatic aldehydes.</jats:p>
収録刊行物
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- Angewandte Chemie International Edition in English
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Angewandte Chemie International Edition in English 15 (11), 639-647, 1976-11
Wiley
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詳細情報 詳細情報について
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- CRID
- 1364233269038035840
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- NII論文ID
- 30010109451
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- ISSN
- 05700833
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- データソース種別
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