Predissociation of oxygen in the <i>B</i> 3Σ−<i>u</i> state

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  • S. S-L. Chiu
    Department of Chemistry, University of Hong Kong, Hong Kong
  • A. S-C. Cheung
    Department of Chemistry, University of Hong Kong, Hong Kong
  • M. Finch
    Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138
  • M. J. Jamieson
    Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138
  • K. Yoshino
    Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138
  • A. Dalgarno
    Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138
  • W. H. Parkinson
    Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138

抄録

<jats:p>The predissociation linewidths and level shifts of vibrational levels of three oxygen isotopic molecules 16O2, 16O18O, and 18O2 arising from the interactions of the B 3Σ−u state with the four repulsive states 5Πu, 3Σ+u, 3Πu, and 1Πu, have been calculated. A set of parameters characterizing these interactions has been determined. Good agreement between calculated and experimental predissociation widths and shifts has been obtained for all the three isotopic molecules.</jats:p>

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