Theory of unsymmetric polymer–polymer interfaces

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Abstract

<jats:p>Solutions have been obtained to equations which described the interface between two immiscible polymers and are more general than the equations first introduced by Helfand and Tagami. Gaussian random−walk statistics are assumed for the macromolecules. As a consequence of the present work, limitations of the earlier theory are removed, particularly the assumption that the properties of the two polymers when pure are identical. Calculations are performed for a variety of polymers and comparison with experiment is made.</jats:p>

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