Point defect generation during high temperature annealing of the Si-SiO2 interface

  • R. A. B. Devine
    Centre National d’Etudes des Télécommunications, France Télécom, BP 98, 38243 Meylan, France
  • D. Mathiot
    Centre National d’Etudes des Télécommunications, France Télécom, BP 98, 38243 Meylan, France
  • W. L. Warren
    Sandia National Laboratories, Albuquerque, New Mexico 87185
  • D. M. Fleetwood
    Sandia National Laboratories, Albuquerque, New Mexico 87185
  • B. Aspar
    LETI/DTA, Centre d’Etudes Nucléaires de Grenoble, BP 85 X, 38041 Grenoble Cedex, France

抄録

<jats:p>Spectroscopic identification of the microscopic defects responsible for annealing induced degradation of the oxide in Si/SiO2/Si structures is presented. Hole injection or x irradiation reveals the presence of oxygen-vacancy centers and oxygen-vacancy center/Si interstitial complexes in the oxide following annealing. O related donors in the Si substrate are also present. These defects result from the diffusion of O from the SiO2 network into the Si; the primary driving force for O diffusion is the difference in the chemical potential of the O in the two phases.</jats:p>

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