Changes in the Soft X-Ray <i>L</i> Emission Spectra with Oxidation of the First Series Transition Metals

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  • David W. Fischer
    Air Force Materials Laboratory, Research and Technology Division, Wright-Patterson Air Force Base, Ohio

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<jats:p>Changes which occur in peak positions, band shapes, and intensities with oxidation are presented for the five main L emission lines from the first-series transition metals. It is shown that the L bands shift in wave-length when going from metal to oxide, the amount of shift depending on the metal target and its state of oxidation. The dependence of the LII/LIII intensity ratio on accelerating potential, valence state, and atomic number are also presented and discussed.</jats:p> <jats:p>A flat-crystal vacuum spectrometer with electron excitation and a thin-window flow-proportional counter was used to obtain the data.</jats:p>

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