Solution Properties of Single-Walled Carbon Nanotubes

DOI Web Site 被引用文献62件
  • Jian Chen
    Departments of Chemistry and Physics, Center for Applied Energy Research and Advanced Carbon Materials Center, University of Kentucky, Lexington, KY 40506, USA.
  • Mark A. Hamon
    Departments of Chemistry and Physics, Center for Applied Energy Research and Advanced Carbon Materials Center, University of Kentucky, Lexington, KY 40506, USA.
  • Hui Hu
    Departments of Chemistry and Physics, Center for Applied Energy Research and Advanced Carbon Materials Center, University of Kentucky, Lexington, KY 40506, USA.
  • Yongsheng Chen
    Departments of Chemistry and Physics, Center for Applied Energy Research and Advanced Carbon Materials Center, University of Kentucky, Lexington, KY 40506, USA.
  • Apparao M. Rao
    Departments of Chemistry and Physics, Center for Applied Energy Research and Advanced Carbon Materials Center, University of Kentucky, Lexington, KY 40506, USA.
  • Peter C. Eklund
    Departments of Chemistry and Physics, Center for Applied Energy Research and Advanced Carbon Materials Center, University of Kentucky, Lexington, KY 40506, USA.
  • Robert C. Haddon
    Departments of Chemistry and Physics, Center for Applied Energy Research and Advanced Carbon Materials Center, University of Kentucky, Lexington, KY 40506, USA.

抄録

<jats:p>Naked metallic and semiconducting single-walled carbon nanotubes (SWNTs) were dissolved in organic solutions by derivatization with thionychloride and octadecylamine. Both ionic (charge transfer) and covalent solution-phase chemistry with concomitant modulation of the SWNT band structure were demonstrated. Solution-phase near-infrared spectroscopy was used to study the effects of chemical modifications on the band gaps of the SWNTs. Reaction of soluble SWNTs with dichlorocarbene led to functionalization of the nanotube walls.</jats:p>

収録刊行物

  • Science

    Science 282 (5386), 95-98, 1998-10-02

    American Association for the Advancement of Science (AAAS)

被引用文献 (62)*注記

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