Crystal Structure of the Solid Electrolyte, RbAg ₄ I ₅

• S. Geller

  North American Aviation Science Center, Thousand Oaks, California

抄録

The crystal structure of the solid electrolyte RbAg 4 I 5 has been determined from single-crystal x-ray diffraction counter data. There are four RbAg 4 I 5 in a cubic unit cell with a = 11.24 Å. The structure refinement, by least squares, is based on space group P 4 1 3 ( O 7 ). The arrangement of the iodide ions is similar to that of the manganese atoms in β-manganese, and provides 56 iodide tetrahedra per unit cell, which share faces in such manner as to provide diffusion paths for the silver ions. The occurrence of the two low-temperature phases of RbAg 4 I 5 has been established by x-ray diffraction and optical examination.

収録刊行物

• Science

  Science 157 (3786), 310-312, 1967-07-21

  American Association for the Advancement of Science (AAAS)

キーワード

• Multidisciplinary

詳細情報

• CRID: 1364233269281276032
• NII論文ID: 30020490441
• DOI: 10.1126/science.157.3786.310
• ISSN: 10959203
• ISSN: 00368075
• Web Site: https://www.science.org/doi/pdf/10.1126/science.157.3786.310
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