ELECTROCHEMICAL STUDIES ON TITANIUM IN MOLTEN LiCl–KCl EUTECTIC

• R. Baboian

• D. L. Hill

• R. A. Bailey

抄録

The methods of potentiometry and polarography have been used to study the Ti(II) and Ti(III) ions in solution in the LiCl–KCl eutectic at 450 °C and 550 °C. Solutions of Ti(II) were prepared by anodic dissolution of Ti metal, and Ti(III) solutions by coulometric titration of Ti(II) by Pt(II). Apparent standard electrode potentials were measured for the Ti(II)/Ti and Ti(III)/Ti(II) couples against the Pt(II)/Pt and Ag(I)/Ag reference electrodes. Values obtained on the mole fraction scale with a Pt(II)/Pt reference electrode were[Formula: see text]Polarographic waves for oxidation and reduction of Ti(II), and for reduction of Ti(III), were observed.

収録刊行物

• Canadian Journal of Chemistry

  Canadian Journal of Chemistry 43 (1), 197-205, 1965-01-01

  Canadian Science Publishing

キーワード

• Organic Chemistry
• General Chemistry
• Catalysis

詳細情報

• CRID: 1360581244451025664
• NII論文ID: 30021716342
• DOI: 10.1139/v65-023
• ISSN: 14803291
• ISSN: 00084042
• Web Site: http://www.nrcresearchpress.com/doi/pdf/10.1139/v65-023
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