Crystal and Electrical Characterizations of Epitaxial Ce<sub>X</sub>Zr<sub>1-X</sub>O<sub>2</sub> Buffer Layer for the Metal/Ferroelectric/Insulator/Semiconductor Field Effect Transistor

  • Hirai Tadahiko
    LSI Laboratories, Asahi Chemical Industry Co., Ltd., 2–1 Samejima, Fuji, Shizuoka 416, Japan
  • Nagashima Kazuhito
    The School of Science and Engineering, Waseda University, 3–4–1 Ohkubo, Shinjuku–ku, Tokyo 169, Japan
  • Koike Hiroshi
    The School of Science and Engineering, Waseda University, 3–4–1 Ohkubo, Shinjuku–ku, Tokyo 169, Japan
  • Matsuno Shinya
    Analytical Research Center, Asahi Chemical Industry Co., Ltd., 2–1 Samejima, Fuji, Shizuoka 416, Japan
  • Tarui Yasuo
    The School of Science and Engineering, Waseda University, 3–4–1 Ohkubo, Shinjuku–ku, Tokyo 169, Japan

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タイトル別名
  • Crystal and Electrical Characterizations of Epitaxial CeXZr1-XO2 Buffer Layer for the Metal/Ferroelectric/Insulator/Semiconductor Field Effect Transistor.
  • Crystal and Electrical Characterization

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抄録

We evaluated the crystallinities of Ce XZr1- XO2 (X=0.10-0.20) thin films used as intermediate layer for metal/ferroelectric/insulator/semiconductor field effect transistors (MFIS-FETs), using reflection high-energy electron diffraction (RHEED), X-ray diffraction (XRD) and X-ray pole figure measurement. The crystal alignments of Ce XZr1- XO2 films on Si(100) were Ce_ XZr1- XO2[100]//Si[100] or Ce_ XZr1- XO2[100]//Si[001], in the plane. The breakdown field of Ce XZr1- XO2 was about 3 MV/cm (at I=1 nA/cm2). From C-V measurements, it was found that the electrical properties of the intermediate layers of the MFIS-FETs were good. Oriented perovskite PbTiO3 films were deposited on Ce XZr1- XO2/Si(100) substrates by digital chemical vapor deposition (CVD). These PbTiO3 films included many PbTiO3 grains aligned with the [100] or [001] axis parallel to the [101] axis of the Ce XZr1- XO2 crystals at the plane in the PbTiO3/Ce XZr1- XO2 interface. From C-V measurements of an Al/PbTiO3/Ce XZr1- XO2/Si(100) sample, we obtained a threshold hysteresis (memory window) of about 1.4 V.

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