Sodium Contamination in SiO<sub>2</sub> Films Induced by Plasma Ashing

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<jats:p> A sodium contamination phenomenon in a SiO<jats:sub>2</jats:sub> film caused by O<jats:sub>2</jats:sub> plasma ashing of a resist film was studied using the triangular voltage sweep method and neutron activation analysis. The contaminant sodium atoms have been proven to come from the resist film. The contamination occurs in two stages: (i) Before ashing end point, the sodium atoms dissolve only in the SiO<jats:sub>2</jats:sub> surface layer by 10<jats:sup>12</jats:sup> cm<jats:sup>-2</jats:sup> surface area density or less. (ii) After the endpoint, the sodium amount in the SiO<jats:sub>2</jats:sub> film increases markedly and eventually saturates at 10<jats:sup>13</jats:sup>–10<jats:sup>14</jats:sup> cm<jats:sup>-2</jats:sup>. The sodium atoms in the SiO<jats:sub>2</jats:sub> film migrate toward the SiO<jats:sub>2</jats:sub>/Si interface during over-ashing in O<jats:sub>2</jats:sub> plasma. Ashing both in O<jats:sub>2</jats:sub>-CF<jats:sub>4</jats:sub> plasma and in a metal shield cylinder are effective in reducing the sodium transportation rate and in preventing contamination. </jats:p>

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