Cover Picture: Polymerization in Coordination Nanospaces (Chem. Asian J. 1‐2/2006)

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<jats:p>Inspired by Nature and the elegant polymerizations that occur in biological systems, chemists are facing up to the challenge of creating materials with well‐defined nanostructures. In their Focus Review on page 36 ff., S. Kitagawa and co‐workers describe how porous coordination polymers can be prepared with such regular channel structures, whose flexible pores and unique surface potentials allow precisely controlled polymerization and polymer arrangement. The cover picture represents polystyrene in the cavity of [Zn<jats:sub>2</jats:sub>(1,4‐dicarboxylate)<jats:sub>2</jats:sub>(triethylenediamine)]<jats:sub><jats:italic>n</jats:italic></jats:sub>. Polymerization of styrene in these nanochannels exhibits living radical nature and thus suggests the possibility of molecular‐weight control.</jats:p>

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