Enantioselectivity of the metabolism of some monoterpenic components of coniferous tree resin by <i>Armillariella mellea</i> (honey fungus)

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<jats:title>Abstract</jats:title><jats:p>Transformation of (±)α‐pinene, (±)α‐terpineol, and (±)α‐limonene by <jats:italic>Armillariella mellea</jats:italic> proceeds enatio‐selectively. (±)α‐Pinene oxidizes (via α‐terpineol) (to (4S)‐<jats:italic>trans</jats:italic>‐sobrerol faster than to (4R)‐isomer. (4R)‐<jats:italic>Trans</jats:italic>‐sobrerol and (4S)‐1,2,8‐<jats:italic>p</jats:italic>‐menthantriol are formed in excess from (±)α‐terpineol, whilst transformation of (±)‐limonene yields an excess of (4R) 8‐<jats:italic>p</jats:italic>‐menthene‐1,2‐diol.</jats:p>

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