Ambipolar Low-bandgap Copolymers Consisting of Dithienoketopyrrole for All-Polymer Solar Cells
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- Ide Marina
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University
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- Koizumi Yoshihiko
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University
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- Saeki Akinori
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University PRESTO-JST
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- Seki Shu
- Department of Applied Chemistry, Graduate School of Engineering, Osaka University
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Abstract
The new low-band gap copolymers containing electron-accepting thienoisoindigo (TIDG) exhibit the low-lying lowest unoccupied molecular orbital (LUMO) at -3.8 eV. This envisions their use as n-type polymer in combination with typical p-type regioregular poly(3-hexylthiophene) (P3HT) towards all-polymer organic photovoltaics (OPV). The alternating fluorene and TIDG copolymer, PFTIDG, shows the electronic absorption maximum at 744 nm in the film states, of which spectrum is complementary to that of P3HT and thus advantageous for covering the wide solar spectrum. The laser and Xe-flash time-resolved microwave conductivity (TRMC) evaluations were performed for screening the effects of p/n blend ratio and thermal annealing in bulk heterojunction framework. The power conversion efficiency of 0.06% was obtained for pre-annealed P3HT:PFTIDG = 1:1 together with a high open circuit voltage of 0.92 V, which is suggestive of ambipolar characteristics of PFTIDG.
Journal
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- Journal of Photopolymer Science and Technology
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Journal of Photopolymer Science and Technology 26 (2), 217-221, 2013
The Society of Photopolymer Science and Technology(SPST)
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Details 詳細情報について
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- CRID
- 1390001204325543552
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- NII Article ID
- 130004465023
- 40019685585
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- NII Book ID
- AA11576862
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- COI
- 1:CAS:528:DC%2BC3sXhtFalu7jI
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- ISSN
- 13496336
- 09149244
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- NDL BIB ID
- 024660375
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed