Creation of Heterogeneous Cellulose Membranes by Multiple Solvent Replacement

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  • 多段階溶媒置換法を用いたセルロース構造膜の創製
  • タダンカイ ヨウバイ チカンホウ オ モチイタ セルロース コウゾウマク ノ ソウセイ

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Abstract

Cellulose is the most abundant biomass polymer in nature. Recently, cellulose nanofibers and composite- and functional-materials thereof are increasingly investigated. Additionally, the investigation about basics and applications of cellulose/ionic liquid solutions are also actively carried out. However, only membranes with a smooth surface structure similar to cellophane were obtained. We have dissolved cellulose in a mixed solution consisting of ionic liquid and organic solvent. We have evaluated the relationship between dissolution time and solution viscosity. By using a multiple solvent displacement method, we constructed a method to make heterogeneous membranes that were formed by spinodal decomposition. The membrane had a high specific surface area and thus, may be applied to high performance permeation membranes and separation membranes.

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 70 (10), 539-543, 2013

    The Society of Polymer Science, Japan

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