Triplet sensitization mechanisms and intermediates in photodecomposition of diaroyl peroxides 過酸化ジアロイルの光分解における三重項増感機構と中間体
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著者
書誌事項
- タイトル
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Triplet sensitization mechanisms and intermediates in photodecomposition of diaroyl peroxides
- タイトル別名
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過酸化ジアロイルの光分解における三重項増感機構と中間体
- 著者名
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高原, 茂
- 著者別名
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タカハラ, シゲル
- 学位授与大学
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筑波大学
- 取得学位
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理学博士
- 学位授与番号
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博甲第291号
- 学位授与年月日
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1985-03-25
注記・抄録
博士論文
The purposes of this investigation are concentrated at two points from the viewpoint of wide stages of photochemistry. One is to elucidate the mechanisms of photochemical bond cleavage and to clarity the differences among the modes of direct and sensitized photolyses, and thermolyses. The other is to clarity behavior of radicals in solution under or by photoirradiation. Diaroyl peroxides are decomposed thermally 1-5) and photochemically, 6-13, 15-29) and used as radical initiator. The diaroyl peroxides, which have π-electronic systems as chromophores, also known to be decomposed by singlet 26-28, 30) and triplet sensitization. 21-25, 27, 29) It has been claritied that there are some processes leading to he decomposition of diaroyl peroxides ・・・
1984
目次
- 目次 (5コマ目)