NMR studies of the Na[+] exchange kinetics in calix[4]arene, and applications of calix[4]arene to selective Na[+] carrier and Na[+] fluorescent receptor カリックス[4]アレンにおけるNa[+]イオンの化学交換についてのNMRによる動力学的研究とカリックス[4]アレンの選択的なNa[+]キャリアー及び螢光性Na[+]レセプターとしての応用

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Author

    • 神, 隆 ジン, タカシ

Bibliographic Information

Title

NMR studies of the Na[+] exchange kinetics in calix[4]arene, and applications of calix[4]arene to selective Na[+] carrier and Na[+] fluorescent receptor

Other Title

カリックス[4]アレンにおけるNa[+]イオンの化学交換についてのNMRによる動力学的研究とカリックス[4]アレンの選択的なNa[+]キャリアー及び螢光性Na[+]レセプターとしての応用

Author

神, 隆

Author(Another name)

ジン, タカシ

University

北海道大学

Types of degree

理学博士

Grant ID

甲第2832号

Degree year

1990-12-25

Note and Description

博士論文

Table of Contents

  1. Contents / (0003.jp2)
  2. Chapter1.Introduction / p1 (0007.jp2)
  3. 1.1 Historical Introduction / p2 (0008.jp2)
  4. 1.2 Purpose and Outline of the Present Study / p6 (0012.jp2)
  5. 1.3 References / p8 (0014.jp2)
  6. Chapter2.Synthesis and Conformational Properties of Calix[4]arenes / p11 (0017.jp2)
  7. 2.1 Synthesis of Calix[4]arenes / p12 (0018.jp2)
  8. 2.2 Conformational Properties of the CalixC4]arenes / p16 (0022.jp2)
  9. 2.3 References / p26 (0032.jp2)
  10. Chapter3.Complexation Characteristics of the Calix[4]arenes with Alkali-metal Ions / p27 (0033.jp2)
  11. 3.1 Introduction / p28 (0034.jp2)
  12. 3.2 Extraction of Alkali-metal Ions from Water to Dichloromethane by the Calix[4]arenes / p28 (0034.jp2)
  13. 3.3 Characterization of the Calix[4]arene Complexes with Alkali-metal Ions using ¹H NMR Technique / p31 (0037.jp2)
  14. 3.4 Characterization of Binding Sites of Alkali-metal Ions in the Calix[4]arenes / p36 (0042.jp2)
  15. 3.5 References / p38 (0044.jp2)
  16. Chapter4.Dynamics of Na⁺ Ion Exchange in p-tert-butylcalix[4]arene Tetraethylacetate in Aprotic Solvents / p39 (0045.jp2)
  17. 4.1 Effects of Sodium Ion Exchange Reaction on ²³Na Longitudinal Magnetization Recovery and ¹H NMR Spectra / p40 (0046.jp2)
  18. 4.2 Solvent Effects on Na⁺ Exchange Kinetics / p61 (0067.jp2)
  19. 4.3 The Influence of Kinetic Factor on the Na⁺/K⁺ Selectivity / p68 (0074.jp2)
  20. 4.4 References / p75 (0081.jp2)
  21. Chapter5.Selective Na⁺ Transport through Phospholipid Bilayers by Ionophoric Calix[4]arene / p77 (0083.jp2)
  22. 5.1 Introduction / p78 (0084.jp2)
  23. 5.2 Apparatus for Ion Transport Measurements using Phospholipid Bilayer Membranes / p79 (0085.jp2)
  24. 5.3 Measurements of Electric Currents Induced by Ion Transport / p81 (0087.jp2)
  25. 5.4 Ion Transport Mechanism in Phospholipid Bilayer Membranes / p83 (0089.jp2)
  26. 5.5 References / p87 (0093.jp2)
  27. 6.1 Introduction / p90 (0095.jp2)
  28. 6.2 Design of a New Na⁺ Selective Fluorescent Probe using a Calix[4]arene / p91 (0096.jp2)
  29. 6.3 Synthesis of a New Na⁺ Fluorescent Probe,p-tert-butylcalix[4]arene Bispyrene(CBP) / p94 (0099.jp2)
  30. 6.4 Identification of CBP / p95 (0100.jp2)
  31. 6.5 Fluorescence Emission Properties of CBP / p98 (0103.jp2)
  32. 6.6 References / p110 (0115.jp2)
  33. Chapter7.Summary and Conclusion / p112 (0117.jp2)
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Codes

  • NII Article ID (NAID)
    500000072340
  • NII Author ID (NRID)
    • 8000000072534
  • DOI(NDL)
  • NDLBibID
    • 000000236654
  • Source
    • NDL ONLINE
    • NDL Digital Collections

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