Studies on syntheses and complexing ability of novel polyether-type host compounds 新規ポリエーテル型ホスト化合物の合成と錯形成能に関する研究

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著者

    • 脇田, 龍平 ワキタ, リュウヘイ

書誌事項

タイトル

Studies on syntheses and complexing ability of novel polyether-type host compounds

タイトル別名

新規ポリエーテル型ホスト化合物の合成と錯形成能に関する研究

著者名

脇田, 龍平

著者別名

ワキタ, リュウヘイ

学位授与大学

大阪大学

取得学位

工学博士

学位授与番号

甲第4325号

学位授与年月日

1991-03-26

注記・抄録

博士論文

目次

  1. Contents / p4 (0005.jp2)
  2. General Introduction / p1 (0006.jp2)
  3. Chapter1 New Type of Ionophores for Lithium Ion:N-Pivot Lariat Ethers Based on Monoaza-14-crown-4 / p3 (0007.jp2)
  4. 1-1 Introduction / p3 (0007.jp2)
  5. 1-2 Preparation of N-Pivot Lariat Ethers / p4 (0008.jp2)
  6. 1-3 Transport Experiment of Alkali Metal Ion / p4 (0008.jp2)
  7. 1-4 Solvent Extraction of Alkali Metal Picrate / p7 (0009.jp2)
  8. 1-5 Experimental / p8 (0010.jp2)
  9. 1-6 References / p12 (0012.jp2)
  10. Chapter2 C-Pivot Lariat Ethers Bearing Electron-Donating Side Arm as Li⁺Selective Extractants / p14 (0013.jp2)
  11. 2-1 Introduction / p14 (0013.jp2)
  12. 2-2 Preparation of C-Pivot Lariat Ethers / p15 (0013.jp2)
  13. 2-3 Solvent Extraction of Alkali Metal Picrate / p18 (0015.jp2)
  14. 2-4 Determination of Extraction Equilibrium Constants / p21 (0016.jp2)
  15. 2-5 Liquid Membrane Transport / p22 (0017.jp2)
  16. 2-6 Conclusion / p23 (0017.jp2)
  17. 2-7 Experimental / p23 (0017.jp2)
  18. 2-8 References / p32 (0022.jp2)
  19. Chapter3 A Facile Synthesis of N-Unsubstituted Monoaza-15-crown-5 with a Bromomethyl Group / p34 (0023.jp2)
  20. 3-1 Introduction / p34 (0023.jp2)
  21. 3-2 Preparation of N-Unsubstituted with a Bromomethyl Group and N-Alkylation Reaction / p34 (0023.jp2)
  22. 3-3 Experimental / p35 (0023.jp2)
  23. 3-4 References / p38 (0025.jp2)
  24. Chapter4 Selective Transport of Lithium Ion by Acyclic Carboxylic Ionophore with Quinaldate Moiety Through Bulk Liquid Membrane / p41 (0026.jp2)
  25. 4-1 Introduction / p41 (0026.jp2)
  26. 4-2 Preparation of Ionophores / p42 (0027.jp2)
  27. 4-3 Liquid Membrane Transport of Alkali Metal Ion / p43 (0027.jp2)
  28. 4-4 Mechanism of Proton-driven Cation Transport / p46 (0029.jp2)
  29. 4-5 Influence of Solvent / p48 (0030.jp2)
  30. 4-6 Liquid Membrane Transport of Alkaline Earth Metal Ion / p49 (0030.jp2)
  31. 4-7 Conclusion / p50 (0031.jp2)
  32. 4-8 Experimental / p51 (0031.jp2)
  33. 4-9 References / p55 (0033.jp2)
  34. Chapter5 Pseudo Cyclic Ionophores:〝Binary-Effect〝of Quinolinyloxy Groups at Both Ends of Oligoethylene Glycols on Conformational Stabilization of Their Complexes with Alkali Metal Salts / p57 (0034.jp2)
  35. 5-1 Introduction / p57 (0034.jp2)
  36. 5-2 Preparation of Acyclic Ionophore / p57 (0034.jp2)
  37. 5-3 Solvent Extraction / p58 (0035.jp2)
  38. 5-4 Determination of Stability Constant / p60 (0036.jp2)
  39. 5-5 Bulk Liquid Membrane Transport / p61 (0036.jp2)
  40. 5-6 Effect of Quinolinyloxy End Group for Stability of Complex / p62 (0037.jp2)
  41. 5-7 Conclusion / p67 (0039.jp2)
  42. 5-8 Experimental / p67 (0039.jp2)
  43. 5-9 References / p74 (0043.jp2)
  44. Chapter6 Epochal Extractabilities of Acyclic Ionophores:Suitable Arrangement of Donor Atoms and Stabilizing Effect by Aromatic Stacking / p76 (0044.jp2)
  45. 6-1 Introduction / p76 (0044.jp2)
  46. 6-2 Preparation of Acyclic Host Compounds / p77 (0044.jp2)
  47. 6-3 Solvent Extraction of Alkali Metal Picrate / p77 (0044.jp2)
  48. 6-4 Complexing-induced Changes in Chemical Shifts of Ionophores in ¹H NMR / p79 (0045.jp2)
  49. 6-5 1-D NOE Differential Spectra / p80 (0046.jp2)
  50. 6-6 ¹³C T₁ Relaxation Times / p82 (0047.jp2)
  51. 6-7 Experimental / p84 (0048.jp2)
  52. 6-8 References / p87 (0049.jp2)
  53. Conclusion / p89 (0050.jp2)
  54. Acknowledgment / p91 (0051.jp2)
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各種コード

  • NII論文ID(NAID)
    500000075760
  • NII著者ID(NRID)
    • 8000000075960
  • DOI(NDL)
  • 本文言語コード
    • und
  • NDL書誌ID
    • 000000240074
  • データ提供元
    • 機関リポジトリ
    • NDL ONLINE
    • NDLデジタルコレクション

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