Studies on syntheses and complexing ability of novel polyether-type host compounds 新規ポリエーテル型ホスト化合物の合成と錯形成能に関する研究
Access this Article
Search this Article
Author
Bibliographic Information
- Title
-
Studies on syntheses and complexing ability of novel polyether-type host compounds
- Other Title
-
新規ポリエーテル型ホスト化合物の合成と錯形成能に関する研究
- Author
-
脇田, 龍平
- Author(Another name)
-
ワキタ, リュウヘイ
- University
-
大阪大学
- Types of degree
-
工学博士
- Grant ID
-
甲第4325号
- Degree year
-
1991-03-26
Note and Description
博士論文
Table of Contents
- Contents / p4 (0005.jp2)
- General Introduction / p1 (0006.jp2)
- Chapter1 New Type of Ionophores for Lithium Ion:N-Pivot Lariat Ethers Based on Monoaza-14-crown-4 / p3 (0007.jp2)
- 1-1 Introduction / p3 (0007.jp2)
- 1-2 Preparation of N-Pivot Lariat Ethers / p4 (0008.jp2)
- 1-3 Transport Experiment of Alkali Metal Ion / p4 (0008.jp2)
- 1-4 Solvent Extraction of Alkali Metal Picrate / p7 (0009.jp2)
- 1-5 Experimental / p8 (0010.jp2)
- 1-6 References / p12 (0012.jp2)
- Chapter2 C-Pivot Lariat Ethers Bearing Electron-Donating Side Arm as Li⁺Selective Extractants / p14 (0013.jp2)
- 2-1 Introduction / p14 (0013.jp2)
- 2-2 Preparation of C-Pivot Lariat Ethers / p15 (0013.jp2)
- 2-3 Solvent Extraction of Alkali Metal Picrate / p18 (0015.jp2)
- 2-4 Determination of Extraction Equilibrium Constants / p21 (0016.jp2)
- 2-5 Liquid Membrane Transport / p22 (0017.jp2)
- 2-6 Conclusion / p23 (0017.jp2)
- 2-7 Experimental / p23 (0017.jp2)
- 2-8 References / p32 (0022.jp2)
- Chapter3 A Facile Synthesis of N-Unsubstituted Monoaza-15-crown-5 with a Bromomethyl Group / p34 (0023.jp2)
- 3-1 Introduction / p34 (0023.jp2)
- 3-2 Preparation of N-Unsubstituted with a Bromomethyl Group and N-Alkylation Reaction / p34 (0023.jp2)
- 3-3 Experimental / p35 (0023.jp2)
- 3-4 References / p38 (0025.jp2)
- Chapter4 Selective Transport of Lithium Ion by Acyclic Carboxylic Ionophore with Quinaldate Moiety Through Bulk Liquid Membrane / p41 (0026.jp2)
- 4-1 Introduction / p41 (0026.jp2)
- 4-2 Preparation of Ionophores / p42 (0027.jp2)
- 4-3 Liquid Membrane Transport of Alkali Metal Ion / p43 (0027.jp2)
- 4-4 Mechanism of Proton-driven Cation Transport / p46 (0029.jp2)
- 4-5 Influence of Solvent / p48 (0030.jp2)
- 4-6 Liquid Membrane Transport of Alkaline Earth Metal Ion / p49 (0030.jp2)
- 4-7 Conclusion / p50 (0031.jp2)
- 4-8 Experimental / p51 (0031.jp2)
- 4-9 References / p55 (0033.jp2)
- Chapter5 Pseudo Cyclic Ionophores:〝Binary-Effect〝of Quinolinyloxy Groups at Both Ends of Oligoethylene Glycols on Conformational Stabilization of Their Complexes with Alkali Metal Salts / p57 (0034.jp2)
- 5-1 Introduction / p57 (0034.jp2)
- 5-2 Preparation of Acyclic Ionophore / p57 (0034.jp2)
- 5-3 Solvent Extraction / p58 (0035.jp2)
- 5-4 Determination of Stability Constant / p60 (0036.jp2)
- 5-5 Bulk Liquid Membrane Transport / p61 (0036.jp2)
- 5-6 Effect of Quinolinyloxy End Group for Stability of Complex / p62 (0037.jp2)
- 5-7 Conclusion / p67 (0039.jp2)
- 5-8 Experimental / p67 (0039.jp2)
- 5-9 References / p74 (0043.jp2)
- Chapter6 Epochal Extractabilities of Acyclic Ionophores:Suitable Arrangement of Donor Atoms and Stabilizing Effect by Aromatic Stacking / p76 (0044.jp2)
- 6-1 Introduction / p76 (0044.jp2)
- 6-2 Preparation of Acyclic Host Compounds / p77 (0044.jp2)
- 6-3 Solvent Extraction of Alkali Metal Picrate / p77 (0044.jp2)
- 6-4 Complexing-induced Changes in Chemical Shifts of Ionophores in ¹H NMR / p79 (0045.jp2)
- 6-5 1-D NOE Differential Spectra / p80 (0046.jp2)
- 6-6 ¹³C T₁ Relaxation Times / p82 (0047.jp2)
- 6-7 Experimental / p84 (0048.jp2)
- 6-8 References / p87 (0049.jp2)
- Conclusion / p89 (0050.jp2)
- Acknowledgment / p91 (0051.jp2)