Preparation of the polymethacrylates with controlled structures through the detailed analysis of polymerization products メタクリル酸エステル重合体の精密構造解析と構造規制
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著者
書誌事項
- タイトル
-
Preparation of the polymethacrylates with controlled structures through the detailed analysis of polymerization products
- タイトル別名
-
メタクリル酸エステル重合体の精密構造解析と構造規制
- 著者名
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右手, 浩一
- 著者別名
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ウテ, コウイチ
- 学位授与大学
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大阪大学
- 取得学位
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工学博士
- 学位授与番号
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乙第5239号
- 学位授与年月日
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1991-01-18
注記・抄録
博士論文
目次
- CONTENTS / (0004.jp2)
- General Introduction / p1 (0005.jp2)
- References / p12 (0011.jp2)
- CHAPTER1.Studies on the Anionic Polymerizations of Methyl Methacrylate Using Totally Deuterated Monomer and Undeuterated or Partially Deuterated Initiator / p14 (0012.jp2)
- 1.1 Introduction / p14 (0012.jp2)
- 1.2 Structures of the PMMAs Prepared with Butylmagnesium Chloride and with Several Other Anionic Initiators / p15 (0012.jp2)
- 1.3 Polymerizations of MMA-d8 with Butyllithium-1,1-d2 and Butylmagnesiutn-1,1-d2 Chloride / p26 (0018.jp2)
- 1.4 Polymerization of MMA-d8 with t-Butylmagnesium Bromide and Formation of a Cyclic Ketone Terminal in Living PMMA Anions / p41 (0025.jp2)
- 1.5 Experimental Part / p45 (0027.jp2)
- References / p47 (0028.jp2)
- CHAPTER2.Living and Highly Isotactic Polymerization of Methyl Methacrylate / p49 (0029.jp2)
- 2.1 Introduction / p49 (0029.jp2)
- 2.2 Living and Highly Isotactic Polymerization of MMA with t-Butylmagnesium Bromide in Toluene / p50 (0030.jp2)
- 2.3 Preparation of Block and Random Copolymers of Methacrylates with High Stereoregularity / p59 (0034.jp2)
- 2.4 Stereochemistry of the Oligomerization of MMA by t-Butylmagnesium Bromide in Toluene at -78℃ / p64 (0037.jp2)
- 2.5 Two-dimensional NMR Spectra of the Isotactic PMMA Prepared with f-Butylmagnesium Bromide and Detailed Examination of Tacticity / p68 (0039.jp2)
- 2.6 Experimental Part / p83 (0046.jp2)
- References / p85 (0047.jp2)
- CHAPTER3.Stereoregular Oligomers of Methyl Methacrylate / p87 (0048.jp2)
- 3.1 Introduction / p87 (0048.jp2)
- 3.2 ¹H and ¹³C NMR Spectra of the Pure lsotactic andPure Syndiotactic Oligomers from Dimer to Octamer / p89 (0049.jp2)
- 3.3 Structure of the lsotactic Trimer in Crystal / p105 (0057.jp2)
- 3.4 SupercriticalFluidChromatography oftheStereoregular Oligomers of MMA / p112 (0061.jp2)
- 3.5 Experimental Part / p118 (0064.jp2)
- References / p120 (0065.jp2)
- CHAPTER4.Analysis of Polymers by On-line GPC/NMR / p122 (0066.jp2)
- 4.1 Introduction / p122 (0066.jp2)
- 4.2 Instrumentation for the On-line GPC/NMR Method / p123 (0066.jp2)
- 4.3 Determination of Molecular Weight and Its Distribution by Absolute Calibration Method Using the PMMAs with Weii-Defined Structure / p125 (0067.jp2)
- 4.4 Molecular Weight Dependence of Tacticity of the PMMAs Prepared by Anionic Initiators / p131 (0070.jp2)
- 4.5 Molecular Weight Dependence of Chemical Composition of the Copolymers of Methacrylates / p137 (0073.jp2)
- 4.6 On-line GPC/NMR Analysis of the Mixture of Chloral Oligomers / p145 (0077.jp2)
- 4.7 Experimental Part / p149 (0079.jp2)
- References / p150 (0080.jp2)
- Publication List / p151 (0080.jp2)
