Studies on structures and stabilities of carbocationic intermediates and stable carbocations 炭素陽イオン中間体ならびに安定炭素陽イオンの構造と安定性に関する研究
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著者
書誌事項
- タイトル
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Studies on structures and stabilities of carbocationic intermediates and stable carbocations
- タイトル別名
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炭素陽イオン中間体ならびに安定炭素陽イオンの構造と安定性に関する研究
- 著者名
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猪飼, 慶三
- 著者別名
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イカイ, ケイゾウ
- 学位授与大学
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京都大学
- 取得学位
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工学博士
- 学位授与番号
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甲第4874号
- 学位授与年月日
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1991-06-29
注記・抄録
博士論文
目次
- 論文目録 / (0001.jp2)
- Contents / p3 (0007.jp2)
- Preface / p5 (0008.jp2)
- Acknowledgments / p10 (0011.jp2)
- List of Publications / p11 (0011.jp2)
- Part1.Stability and Structure of Carbocation Intermediates in the [数式] Phenolysis / (0012.jp2)
- Chapter1.The Number and the Stability of Carbocation Intermediate in the [数式] Phenolysis:Salt Effect on Retentive Phenolyses of Optically Active 2,2-Dimethyl-1-(p-substituted phenyl)-propyl p-Nitrobenzoates / p3 (0013.jp2)
- Chapter2.The Pattern of Salt Effect and the Number of Ion-Pair Intermediates in the [数式] Solvolysis:Salt Effect on the Retentive Phenolyses of 1-(p-Substituted phenyl)ethyl p-Nitrobenzoates / p20 (0022.jp2)
- Chapter3.The Mechanism and the Structure of the First Ion-Pair Intermediate:Reinvestigation of the Retentive Phenolysis of 1-Phenylethyl Chloride / p37 (0030.jp2)
- Chapter4.The Mechanism and the Structure of the Second Ion-Pair Intermediate:The Methanol-perturbed Phenolysis of Optically Active 2,2-Dimethyl-1-(p-methoxyphenyl)propyl p-Nitrobenzoate / p63 (0043.jp2)
- Part2.Evaluation of π-Conjugative Stabilization of α-Keto Carbocations / (0059.jp2)
- Chapter5.Evaluation of the π-Conjugative Effect of the 2-Methylene and the 2-0xo Substituent on the Stability of Carbocations in the Solvolysis of Bicyclic Bridgehead Derivatives / p97 (0060.jp2)
- Part3.Stereomutation of some Alkyltropylium Ions / (0070.jp2)
- Chapter6.Stereomutation of endo-2-Phenyl-endo-6-Tropylio-bicyclo[2.2.2]octane to the exo-6-Tropylio Isomer:Steric Repulsion Between the Phenyl and Tropylium Rings Showing Intramolecular Charge-Transfer / p119 (0071.jp2)
- Chapter7.Stereomutation of 7-Tropylionorbornane,2-Tropyliobicyclo[2.2.2]octane, and 2-Tropylio-adamantane:Evidence for the Intermediacy of Heptafulvenes in the Stereomutation / p131 (0077.jp2)
- Summary / p159 (0091.jp2)