Studies on zero-field splitting in metal complexes : its relation to geometric distortion and the nature of metal-ligand bonding 金属錯体の零磁場分裂に関する研究 : 構造の歪み及び金属・配位子間結合の性質との関係

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Title: Studies on zero-field splitting in metal complexes : its relation to geometric distortion and the nature of metal-ligand bonding

博士論文

論文目録 / (0001.jp2)
Contents / p2 (0005.jp2)
Preface / p3 (0006.jp2)
Chapter I.Introduction / p1 (0007.jp2)
Chapter II.Experimental / p4 (0010.jp2)
1.Materials / p4 (0010.jp2)
2.Measurements / p5 (0011.jp2)
3.Foundations of Analyses / p6 (0012.jp2)
Chapter III.Zero-Field Splitting in Simple Complexes / p12 (0018.jp2)
1.General Concept / p12 (0018.jp2)
2.Normal Coordinate Expression of ZFS / p15 (0021.jp2)
3.Application / p22 (0028.jp2)
4.Summary / p28 (0034.jp2)
Chapter IV.Zero-Field Splitting in Cobalt Thiolates Polycrystalline ESR and Susceptibility Studies / p29 (0035.jp2)
1.Background of Cobalt-Thiolate Complexes / p29 (0035.jp2)
2.Polycrystalline Susceptibility and ESR Results / p35 (0041.jp2)
3.Summary / p42 (0048.jp2)
Chapter V.ZFS of Cobalt-Thiolate Complexes II Single-Crystal ESR, Susceptibility, and Polarized Absorption Studies / p43 (0049.jp2)
1.Results and Analyses / p43 (0049.jp2)
2.Properties of (Ph₄P)₂〔Co(SPh)₄〕 / p52 (0058.jp2)
3.Metal-Thiolate Bonding Properties / p57 (0063.jp2)
4.Summary / p62 (0068.jp2)
References / p63 (0069.jp2)
Appendix / p67 (0073.jp2)
X-ray Structural Data of (Me₄N)₂〔Co(SPh)₄〕 / p67 (0073.jp2)
MAGNETIC PROPERTIES OF A PENTA-COORDINATED HIGH-SPIN COBALT(II) COMPLEX:ACETATE-N-METHYL-OCTAETHYLPORPHYRINATO-COBALT(II) / p15 (0135.jp2)
Purification and Characterization of Two Types of Fumarase from Escherichia coli / p728 (0139.jp2)

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