In-situ analysis of the kinetic behaviour of mass transport in an osmium-pyridine polymer complex and polypyrrole electropolymerized with surfactant anion オスミウム-ピリジン高分子錯体膜及び界面活性アニオンを含むポリピロール膜における物質異動の動力学的挙動のその場解析
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著者
書誌事項
- タイトル
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In-situ analysis of the kinetic behaviour of mass transport in an osmium-pyridine polymer complex and polypyrrole electropolymerized with surfactant anion
- タイトル別名
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オスミウム-ピリジン高分子錯体膜及び界面活性アニオンを含むポリピロール膜における物質異動の動力学的挙動のその場解析
- 著者名
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Andrew J. Kelly
- 著者別名
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アンドリュー ケリー
- 学位授与大学
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東京農工大学
- 取得学位
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工学博士
- 学位授与番号
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甲第21号
- 学位授与年月日
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1992-06-25
注記・抄録
博士論文
目次
- Contents / (0003.jp2)
- Chapter1:Introduction / (0005.jp2)
- 1.1 Electron transfer in electroactive polymers / p1 (0006.jp2)
- 1.2 Mass transport in e1ectroactive polymers / p5 (0010.jp2)
- 1.3 Methods of measurement of charge transport.in e1ectroactive polymer films. / p6 (0011.jp2)
- 1.4 In-situ mass measurements using the electrochemical quartz crystal microbalance (EQCM) to the measurement of mass transport. / p11 (0016.jp2)
- 1.5 References / p17 (0022.jp2)
- Chapter2:In-situ EQCM determination of mass transport accompanying electron transfer in an osmium-pyridine polymer film in perchlorate containing electrolyte solutions. / (0028.jp2)
- 2.1 Introduction / p23 (0029.jp2)
- 2.2 Experimental section / p25 (0031.jp2)
- 2.3 In aqueous perchlorate containing solutions / p29 (0035.jp2)
- 2.4 In non-aqueous perchlorate containing solutions / p45 (0051.jp2)
- 2.5 Correlation of[数式]and mass transport / p48 (0054.jp2)
- 2.6 Investigation of the EQCM response of the[数式]and[数式]redox states / p51 (0057.jp2)
- 2.7 Summary / p59 (0065.jp2)
- 2.8 Conclusions / p60 (0066.jp2)
- 2.9 References / p61 (0067.jp2)
- Chapter3:Solvent and ion transport for osmium polymer complex in various inorganic and organic ion solutions. / (0069.jp2)
- 3.1 Introduction / p63 (0070.jp2)
- 3.2 Experimental section / p64 (0071.jp2)
- 3.3 In aqueous electrolyte solutions containing various anions and cations in aqueous electrolyte solutions / p65 (0072.jp2)
- 3.4 Mass transport in acetonitrile solutions / p88 (0095.jp2)
- 3.5 Electromediation of ferrocyanide / p93 (0100.jp2)
- 3.6 Summary / p97 (0104.jp2)
- 3.7 Conclusion / p98 (0105.jp2)
- 3.8 References / p99 (0106.jp2)
- Chapter4 Admittance measurements with the quartz crystal/osmium pyridine polymer film / (0108.jp2)
- 4.1 Introduction / p101 (0109.jp2)
- 4.2 Experimental Section / p102 (0110.jp2)
- 4.3 Determination of equivalent electric circuit parameters / p103 (0111.jp2)
- 4.4 Ex-situ measurement of the admittance parameters / p106 (0114.jp2)
- 4.5 In-situ dependence of the admittance response / p109 (0117.jp2)
- 4.6 Summary / p115 (0123.jp2)
- 4.7 Conclusion / p116 (0124.jp2)
- 4.8 References / p117 (0125.jp2)
- Chapter6 Kinetic behaviour of mass transport in polypyrrole films electropolymerized with surfactant anion. / (0126.jp2)
- 5.1 Introduction / p118 (0127.jp2)
- 5.2 Experimental section / p119 (0128.jp2)
- 5.3 Results and Discussion / p123 (0132.jp2)
- 5.4 Summary / p147 (0156.jp2)
- 5.5 Conclusion / p148 (0157.jp2)
- 5.6 References / p149 (0158.jp2)
- Chapter6 Conclusion / p150 (0159.jp2)
- Acknowledgement / p152 (0162.jp2)