Properties of Δ-, and Λ-[Ru(S-am)(bpy)[2]][+] complexes (am=Ala, Phg, Leu, Phe or Tyr ligand) in solution originating from (S)-aminoacidato ligand : mechanism of the chromatographic separation, effect of hydration on the stability of the diastereoisomers, and racemization of the phenylalaninato ligand 溶液中におけるΔ-およびΛ-[Ru(S-am)(bpy)[2]][+]錯体(am=Ala,Phg,Leu,PheおよびTyr配位子)の(S)-アミノアシダト配位子に由来する性質 : クロマトグラフィーにおける分離機構、ジアステレオ異性体の安定性におよぼす水和の影響、フェニルアラニナト配位子のラセミ化反応
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Bibliographic Information
- Title
-
Properties of Δ-, and Λ-[Ru(S-am)(bpy)[2]][+] complexes (am=Ala, Phg, Leu, Phe or Tyr ligand) in solution originating from (S)-aminoacidato ligand : mechanism of the chromatographic separation, effect of hydration on the stability of the diastereoisomers, and racemization of the phenylalaninato ligand
- Other Title
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溶液中におけるΔ-およびΛ-[Ru(S-am)(bpy)[2]][+]錯体(am=Ala,Phg,Leu,PheおよびTyr配位子)の(S)-アミノアシダト配位子に由来する性質 : クロマトグラフィーにおける分離機構、ジアステレオ異性体の安定性におよぼす水和の影響、フェニルアラニナト配位子のラセミ化反応
- Author
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永井, 俊
- Author(Another name)
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ナガイ, タカシ
- University
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立教大学
- Types of degree
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博士 (理学)
- Grant ID
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乙第120号
- Degree year
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1993-03-31
Note and Description
博士論文
Table of Contents
- Contents / (0005.jp2)
- Chapter1.Introduction / p1 (0007.jp2)
- Chapter2.Mechanism of the Chromatographic Separation / p10 (0016.jp2)
- Introduction / p10 (0016.jp2)
- Experimental / p11 (0017.jp2)
- Results and discussion / p14 (0020.jp2)
- Chapter3.Effect of Hydration on the Stability of the Diastereoisomers / p37 (0043.jp2)
- Introduction / p37 (0043.jp2)
- Experimental / p39 (0045.jp2)
- Results and discussion / p43 (0049.jp2)
- Chapter4.Racemization of Phenylalaninato Ligand / p56 (0062.jp2)
- Introduction / p56 (0062.jp2)
- Experimental / p56 (0062.jp2)
- Results and discussion / p62 (0068.jp2)
- Chapter5.Conclusion / p72 (0078.jp2)
- References / p75 (0081.jp2)
- Acknowledgements / p80 (0086.jp2)