Studies on electrophilic substitution reactions with phenylthallium crown ether complexes フェニルタリウム-クラウンエーテル錯体による求電子置換反応に関する研究
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著者
書誌事項
- タイトル
-
Studies on electrophilic substitution reactions with phenylthallium crown ether complexes
- タイトル別名
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フェニルタリウム-クラウンエーテル錯体による求電子置換反応に関する研究
- 著者名
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垣内, 史敏
- 著者別名
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カキウチ, フミトシ
- 学位授与大学
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大阪大学
- 取得学位
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博士 (工学)
- 学位授与番号
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甲第4771号
- 学位授与年月日
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1993-03-25
注記・抄録
博士論文
目次
- Contents / p3 (0005.jp2)
- Preface / p1 (0003.jp2)
- List of Publications / p2 (0004.jp2)
- General Introduction / p1 (0006.jp2)
- Chapter1 Electrophilic Thallations of Phenols and Anilines by the Reaction of (18-Crown-6)phenylthallium(III) Diperchlorate / p4 (0008.jp2)
- 1-1 Introduction / p4 (0008.jp2)
- 1-2 Preparation of (Crown Ether)phenylthallium(III) Diperchlorate / p4 (0008.jp2)
- 1-3 Reaction of (Crown Ether)phenylthallium(III) Diperchlorate with Phenol / p5 (0008.jp2)
- 1-4 Reaction of (18-Crown-6)phenylthallium(III) Diperchlorate with Methylsubstituted Phenols / p6 (0009.jp2)
- 1-5 Reaction of (18-Crown-6)phenylthallium(III) Diperchlorate with Phenols containing Good Electron-Donating Group / p9 (0010.jp2)
- 1-6 Reaction with Anisole and Alkylbenzenes / p10 (0011.jp2)
- 1-7 Reaction with Anilines / p11 (0011.jp2)
- 1-8 Experimental Section / p13 (0012.jp2)
- 1-9 References and Notes / p22 (0017.jp2)
- Chapter2 Electrophilic Thallation of Heteroaromatic Compounds Using (18-Crown-6)phenylthallium(III) Diperchlorate / p24 (0018.jp2)
- 2-1 Introduction / p24 (0018.jp2)
- 2-2 Reaction of (18-Crown-6)phenylthallium(III) Diperchlorate with Five-Membered Nitrogen Heterocycles / p25 (0018.jp2)
- 2-3 Reaction with imidazole and N-methylimidazole / p26 (0019.jp2)
- 2-4 Reaction with Thiophenes and Furan / p28 (0020.jp2)
- 2-5 Experimental Section / p30 (0021.jp2)
- 2-6 References and Notes / p37 (0024.jp2)
- Chapter3 Highly Selective Methyl Transfer to Thallium from Methyl Silanes / p39 (0025.jp2)
- 3-1 Introduction / p39 (0025.jp2)
- 3-2 Reaction of (Crown Ether)phenylthallium(III) Diperchlorate with Benzyltrimethylsilane / p39 (0025.jp2)
- 3-3 Reaction with Various Organosilanes Contiaining Trimethylsilyl Group / p41 (0026.jp2)
- 3-4 Intramolecular Trapping of the Silyl Fragment with Hydroxy Group / p41 (0026.jp2)
- 3-5 Experimental Section / p42 (0027.jp2)
- 3-6 References and Notes / p46 (0029.jp2)
- Chapter4 Analysis of Ionic Character of Thallium-Carbon Bonds Formed on the Basis of Spin-Spin Coupling Constant between Thallium Nucleus and Protons / p48 (0030.jp2)
- 4-1 Introduction / p48 (0030.jp2)
- 4-2 Ionic Character of Thallium-Carbon Bonds in (18-Crown-6)diorganothallium(III) Diperchlorate / p48 (0030.jp2)
- 4-3 References / p54 (0033.jp2)
- Conclusion / p55 (0033.jp2)
- Acknowledgement / p57 (0034.jp2)
