Studies on electrophilic substitution reactions with phenylthallium crown ether complexes フェニルタリウム-クラウンエーテル錯体による求電子置換反応に関する研究
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著者
書誌事項
- タイトル
-
Studies on electrophilic substitution reactions with phenylthallium crown ether complexes
- タイトル別名
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フェニルタリウム-クラウンエーテル錯体による求電子置換反応に関する研究
- 著者名
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垣内, 史敏
- 著者別名
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カキウチ, フミトシ
- 学位授与大学
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大阪大学
- 取得学位
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博士 (工学)
- 学位授与番号
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甲第4771号
- 学位授与年月日
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1993-03-25
注記・抄録
博士論文
資料形態 : テキストデータ プレーンテキスト
コレクション : 国立国会図書館デジタルコレクション > デジタル化資料 > 博士論文
目次
- Contents
- Preface
- List of Publications
- General Introduction
- Chapter1 Electrophilic Thallations of Phenols and Anilines by the Reaction of (18-Crown-6)phenylthallium(III) Diperchlorate
- 1-1 Introduction
- 1-2 Preparation of (Crown Ether)phenylthallium(III) Diperchlorate
- 1-3 Reaction of (Crown Ether)phenylthallium(III) Diperchlorate with Phenol
- 1-4 Reaction of (18-Crown-6)phenylthallium(III) Diperchlorate with Methylsubstituted Phenols
- 1-5 Reaction of (18-Crown-6)phenylthallium(III) Diperchlorate with Phenols containing Good Electron-Donating Group
- 1-6 Reaction with Anisole and Alkylbenzenes
- 1-7 Reaction with Anilines
- 1-8 Experimental Section
- 1-9 References and Notes
- Chapter2 Electrophilic Thallation of Heteroaromatic Compounds Using (18-Crown-6)phenylthallium(III) Diperchlorate
- 2-1 Introduction
- 2-2 Reaction of (18-Crown-6)phenylthallium(III) Diperchlorate with Five-Membered Nitrogen Heterocycles
- 2-3 Reaction with imidazole and N-methylimidazole
- 2-4 Reaction with Thiophenes and Furan
- 2-5 Experimental Section
- 2-6 References and Notes
- Chapter3 Highly Selective Methyl Transfer to Thallium from Methyl Silanes
- 3-1 Introduction
- 3-2 Reaction of (Crown Ether)phenylthallium(III) Diperchlorate with Benzyltrimethylsilane
- 3-3 Reaction with Various Organosilanes Contiaining Trimethylsilyl Group
- 3-4 Intramolecular Trapping of the Silyl Fragment with Hydroxy Group
- 3-5 Experimental Section
- 3-6 References and Notes
- Chapter4 Analysis of Ionic Character of Thallium-Carbon Bonds Formed on the Basis of Spin-Spin Coupling Constant between Thallium Nucleus and Protons
- 4-1 Introduction
- 4-2 Ionic Character of Thallium-Carbon Bonds in (18-Crown-6)diorganothallium(III) Diperchlorate
- 4-3 References
- Conclusion
- Acknowledgement
