Stereoselective reactions of organocopper and organozinc reagents 有機銅試薬及び有機亜鉛試薬を用いた立体選択的反応
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Bibliographic Information
- Title
-
Stereoselective reactions of organocopper and organozinc reagents
- Other Title
-
有機銅試薬及び有機亜鉛試薬を用いた立体選択的反応
- Author
-
荒井, 雅之
- Author(Another name)
-
アライ, マサユキ
- University
-
東京工業大学
- Types of degree
-
博士 (理学)
- Grant ID
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甲第2540号
- Degree year
-
1993-03-26
Note and Description
博士論文
Table of Contents
- 論文目録 / (0002.jp2)
- Table of Contents / (0007.jp2)
- Chapter1 General Introduction.Development of Carbon-Carbon Bond Formation Reactions and Asymmetric lnduction / p1 (0011.jp2)
- 1.1 Nucleophilic Addition to α-Chiral Carbonyl Compound / p2 (0012.jp2)
- 1.2 Asymmetric Induction in the Nucleophilic Addition to Chiral Olefins / p5 (0015.jp2)
- Chapter2 High Diastereoselectivity in[化学式]-Allylation of Copper-Zinc Reagents / p14 (0024.jp2)
- 2.1 [化学式]Allylation with δ-Substituted Allylic Chlorides / p14 (0024.jp2)
- 2.2 δ-Substituted Allylic Chloride. Choice of the Substrate / p19 (0029.jp2)
- 2.3 [化学式] Allylation of δ-Alkoxyallylic Chlorides / p24 (0034.jp2)
- 2.4 [化学式] Allylation of δ-Substituted Allylic Chlorides.Steric Effect at Chiral Center / p33 (0043.jp2)
- 2.5 [化学式] Allylation of Silylcopper Reagent / p40 (0050.jp2)
- 2.6 Structure Determination / p41 (0051.jp2)
- 2.7 Conclusion / p47 (0057.jp2)
- 2.8 Experimental Section / p49 (0059.jp2)
- References / p76 (0086.jp2)
- Chapter3 0n the Nature of the Copper-Based[化学式]-Selective Reagents / p79 (0089.jp2)
- 3.1 lntroduction / p79 (0089.jp2)
- 3.2 Experimental Method / p83 (0093.jp2)
- 3.3 NMR Analysis of Copper-Zinc and Copper-Titanium Reagents / p85 (0095.jp2)
- 3.4 Reactivity Analysis of the Copper-Zinc and the Copper-Titanium Reagents / p94 (0104.jp2)
- 3.5 Conclusion / p98 (0108.jp2)
- References / p100 (0110.jp2)
- Chapter4 Copper-Catalyzed Reactions of Organotitanium Reagents.Highly Selective[化学式]-Allylation and Conjugate Addition / p102 (0112.jp2)
- 4.1 Introduction / p102 (0112.jp2)
- 4.2 [化学式]-Allylation Reaction of Organozinc-Based Catalytic Organocopper Reagents / p103 (0113.jp2)
- 4.3 [化学式]-Allylation of Organotitanium-Based Catalytic Organocopper Reagents / p106 (0116.jp2)
- 4.4 Conjugate Addition of Organotitanium-Based Catalytic Organocopper Reagents in the Presence of Me₃SiCl / p112 (0122.jp2)
- 4.5 Conclusion / p115 (0125.jp2)
- 4.6 Experimental Section / p116 (0126.jp2)
- References / p129 (0139.jp2)
- Chapter5 [化学式]-Allylation Reaction of Organozinc Reagents.Highly Regio-and Diastereoselective Reaction / p133 (0143.jp2)
- 5.1 lntroduction / p133 (0143.jp2)
- 5.2 [化学式]-Allylation Reaction of Organozinc Reagents / p135 (0145.jp2)
- 5.3 Asymmetric Induction in the[化学式]-Allylation of Dialkylzinc Reagents / p138 (0148.jp2)
- 5.4 [化学式]-Allylation of δ-Alkoxy Substituted Allylic Chlorides / p144 (0154.jp2)
- 5.5 Conclusion / p146 (0156.jp2)
- 5.6 Experimental Section / p147 (0157.jp2)
- References / p159 (0169.jp2)
- Chapter6 Stereochemistry of the[化学式]-Allylation Reaction / p161 (0171.jp2)
- 6.1 Observed Stereoselectivity in the Present[化学式]-Allylation Reactions / p161 (0171.jp2)
- 6.2 Distinctive Stereochemical Properties of the[化学式]-Allylation Reaction / p164 (0174.jp2)
- 6.3 Mechanism of the Present[化学式]-Allylation / p168 (0178.jp2)
- 6.4 Nucleophilic Carbon Mechanism.Explanation of Stereochemical Behavior / p171 (0181.jp2)
- 6.5 Conclusion / p178 (0188.jp2)
- References / p179 (0189.jp2)
- Chapter7 1,4-Asymmetric Induction in the 1,2-Addition to α,β-Unsaturated Aldehydes in the Presence of Chlorosilane.Vinylogous Cram's Rule / p181 (0191.jp2)
- 7.1 lntroduction / p181 (0191.jp2)
- 7.2 Vinylogous Cram's Rule / p182 (0192.jp2)
- 7.3 Conclusion / p188 (0198.jp2)
- 7.4 Experimental Section / p189 (0199.jp2)