Syntheses and reactions of functionalized α,α-difluorinated aldehyde equivalents 官能基を含むα,α-ジフルオロアルデヒド等価体の合成とその反応
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著者
書誌事項
- タイトル
-
Syntheses and reactions of functionalized α,α-difluorinated aldehyde equivalents
- タイトル別名
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官能基を含むα,α-ジフルオロアルデヒド等価体の合成とその反応
- 著者名
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塚本, 尚
- 著者別名
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ツカモト, タカシ
- 学位授与大学
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東京工業大学
- 取得学位
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博士 (工学)
- 学位授与番号
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甲第2570号
- 学位授与年月日
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1993-03-26
注記・抄録
博士論文
目次
- 論文目録 / (0002.jp2)
- Contents / p2 (0004.jp2)
- Chapter1 Introduction / p1 (0007.jp2)
- References and Notes / p17 (0023.jp2)
- Chapter2 Formylation Reaction of α,α-Difluorinated Reformatsky Reagents / p20 (0026.jp2)
- Introduction / p20 (0026.jp2)
- Reaction Mechanism and Optimization of the Conditions / p22 (0028.jp2)
- CF₂-Containing Hemiacetals and Malonates / p25 (0031.jp2)
- Formylation Reaction of Difluoromethylphosphonate / p28 (0034.jp2)
- Experimental / p32 (0038.jp2)
- References and Notes / p38 (0044.jp2)
- Chapter3 Reaction of α,α-Difluorinated Hemiacetals as Aldehdye Equivalents / p41 (0047.jp2)
- Introduction / p41 (0047.jp2)
- Lewis Acid-promoted Reactions with Nucleophiles / p44 (0050.jp2)
- Horner-Wadsworth-Emmons Reaction / p47 (0053.jp2)
- Nitroaldol Reaction / p48 (0054.jp2)
- Reaction of α,α-Difluoro-a-phosphonoacetaldehdye Ethyl Hemiacetal / p56 (0062.jp2)
- Experimental / p60 (0066.jp2)
- References and Notes / p73 (0079.jp2)
- Chapter4 Synthesis of β,β-Difluorinated Amines from CF₂-Containing N,0-Acetal or Imine / p76 (0082.jp2)
- Introduction / p76 (0082.jp2)
- Difluorinated N,O-Acetal / p83 (0089.jp2)
- Difluorinated N-Benzylamine / p88 (0094.jp2)
- Experimental / p94 (0100.jp2)
- References and Notes / p104 (0110.jp2)
- Chapter5 Synthesis of α,α,α',α'-Tetrafluoroketone A Novel Transition-State Analogue for Carbonate Hydrolysis / p106 (0112.jp2)
- Introduction / p106 (0112.jp2)
- Reformatsky Reaction of Ethyl 4-Chloro-4,4-difluorocrotonate / p111 (0117.jp2)
- Horner-Wadsworth-Emmons Reactions of α,α-Difluoro-b-hydroxyaldehdye Equivalent / p117 (0123.jp2)
- Synthesis of α,α,α',α'-Tetrafluoroketone / p121 (0127.jp2)
- Experimental / p126 (0132.jp2)
- References and Notes / p139 (0145.jp2)
- Chapter6 Conclusion / p141 (0147.jp2)
