Complexation and structure of lanthanoid(Ⅲ) ions in nonaqueous solution 非水溶液中におけるランタノイド(Ⅲ)イオンの錯形成及び構造
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著者
書誌事項
- タイトル
-
Complexation and structure of lanthanoid(Ⅲ) ions in nonaqueous solution
- タイトル別名
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非水溶液中におけるランタノイド(Ⅲ)イオンの錯形成及び構造
- 著者名
-
高橋, 陵太
- 著者別名
-
タカハシ, リョウタ
- 学位授与大学
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東京工業大学
- 取得学位
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博士 (理学)
- 学位授与番号
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甲第2633号
- 学位授与年月日
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1993-03-26
注記・抄録
博士論文
目次
- Contents / (0004.jp2)
- 1 Introduction / p1 (0007.jp2)
- 1.1 Discovery of rare earth elements / p1 (0007.jp2)
- 1.2 Quest for separation reveals chemistry of rare earths / p5 (0011.jp2)
- 1.3 Complex formation of lanthanoid(III) ions with chelating agents in aqueous solution / p6 (0012.jp2)
- 1.4 Coordination geometries of hydrated lanthanoid(III) ions / p8 (0014.jp2)
- 1.5 Lanthanoid(III) ions in nonaqueous solution / p13 (0019.jp2)
- 1.6 Formation of outer or inner-sphere complex in solution / p18 (0025.jp2)
- 1.7 Scandium(III), aluminium(III), gallium(III) and indium(III) ions in water or nonaqueous solution / p20 (0027.jp2)
- 1.8 Experimental aspects / p22 (0029.jp2)
- 1.9 The purpose of this study / p25 (0032.jp2)
- References / p29 (0036.jp2)
- 2 Experimental / p35 (0042.jp2)
- 2.1 Calorimetric measurement / p35 (0042.jp2)
- 2.2 EXAFS measurements / p40 (0047.jp2)
- References / p44 (0051.jp2)
- 3 Thermodynamics of Chloro Complex Formation of Lanthanoid(III) ions in N, N-Dimethylformamide / p45 (0052.jp2)
- 3.1 Introduction / p45 (0052.jp2)
- 3.2 Experimental / p45 (0052.jp2)
- 3.3 Results / p48 (0055.jp2)
- 3.4 Discussion / p58 (0065.jp2)
- References / p61 (0068.jp2)
- 4 Inner-sphere and Outer-sphere Complex Formation of Yttrium(III) and Lanthanoid(III) in N, N-Dimethylformamide / p62 (0069.jp2)
- 4.1 Introduction / p62 (0069.jp2)
- 4.2 Experimental / p63 (0070.jp2)
- 4.3 Results / p66 (0073.jp2)
- 4.4 Discussion / p75 (0082.jp2)
- References / p79 (0086.jp2)
- 5 The Structure of Solvated Lanthanoid(III) Ions in N, N-Dimethylformamide and N, N-Dimethylacetamide, and Complex Formation of Halogeno Lanthanoid(III) in N, N-Dimethylacetamide / p81 (0088.jp2)
- 5.1 Introduction / p81 (0088.jp2)
- 5.2 Experimental / p82 (0089.jp2)
- 5.3 Results / p89 (0096.jp2)
- 5.4 Discussion / p109 (0116.jp2)
- References / p116 (0119.jp2)
- 6 Thiocyanato Complex Formation of Yttrium(III) and Lanthanoid(III) Ions in N, N-Dimethylformamide / p117 (0120.jp2)
- 6.1 Introduction / p117 (0120.jp2)
- 6.2 Experimental / p118 (0121.jp2)
- 6.3 Results / p121 (0124.jp2)
- 6.4 Discussion / p135 (0138.jp2)
- References / p139 (0142.jp2)
- 7 Halogeno and Thiocyanato Complex Formation of Aluminium,Gallium(III) and Indium(III) Ions in N,N-Dimethylformamide / p140 (0143.jp2)
- 7.1 Introduction / p140 (0143.jp2)
- 7.2 Experimental / p141 (0144.jp2)
- 7.3 Results / p144 (0147.jp2)
- 7.4 Discussion / p156 (0159.jp2)
- References / p160 (0163.jp2)
- 8 Conclusion / p161 (0164.jp2)
- Appendix / p167 (0170.jp2)
- List of Publications / (0188.jp2)