The synthesis and properties of modified oligopentafulvenes 修飾オリゴペンタフルベン類の合成と性質
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著者
書誌事項
- タイトル
-
The synthesis and properties of modified oligopentafulvenes
- タイトル別名
-
修飾オリゴペンタフルベン類の合成と性質
- 著者名
-
蔵田, 浩之
- 著者別名
-
クラタ, ヒロユキ
- 学位授与大学
-
大阪大学
- 取得学位
-
博士 (理学)
- 学位授与番号
-
甲第4862号
- 学位授与年月日
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1993-09-27
注記・抄録
博士論文
目次
- CONTENTS / p1 (0003.jp2)
- Chapter One:General Introduction / p1 (0005.jp2)
- 1-1.General Purpose of the Present Study / p1 (0005.jp2)
- 1-2.Recent Development of Oligomers and Polymers of Conjugated Molecules / p2 (0006.jp2)
- 1-3.Oligofulvenes and Oligopentafulvenes as Novel Conjugated Oligomers / p4 (0007.jp2)
- 1-4.On Pentafulvenes / p5 (0007.jp2)
- 1-5.Modified Oligopentafulvenes as Actual Target Molecules / p8 (0009.jp2)
- 1-6.Contents of the Present Thesis / p10 (0010.jp2)
- 1-7.References / p13 (0011.jp2)
- Chapter Two:Selective Lithiation and Functionalization of 6,6-Di(2-thienyl)pentafulvene / p16 (0013.jp2)
- 2-1.introduction / p16 (0013.jp2)
- 2-2.Results and Discussion / p17 (0013.jp2)
- 2-3.Experimental Section / p22 (0016.jp2)
- 2-4.References / p30 (0020.jp2)
- Chapter Three:Tandem Reactions of N,N-Dialkylamides with Organolithium Compounds and Cyclopentadicne. A New Efficient Synthesis of Pentafulvenes / p31 (0020.jp2)
- 3-1.Introduction / p31 (0020.jp2)
- 3-2.Result and Discussion / p32 (0021.jp2)
- 3-3.Scope and Limitation / p35 (0022.jp2)
- 3-4.Experimental Section / p39 (0024.jp2)
- 3-5.References / p45 (0027.jp2)
- Chapter Four:Synthesis and Properties of Oligo-6-(2-thienyl)pentafulvenes and Related Oligothienylpentafulvenes / p46 (0028.jp2)
- 4-1.Introduction / p46 (0028.jp2)
- 4-2.Synthetic Strategies / p46 (0028.jp2)
- 4-3.Synthesis of O1igo-6-(2-thienyl)pentafulvenes / p50 (0030.jp2)
- 4-4.Physical Properties of Oligo-6-(2-thienyl)pentafulvenes / p52 (0031.jp2)
- 4-5.Synthesis of Oligo[6,6-di(2-thienyl)pentafulvene]s / p67 (0038.jp2)
- 4-6.Physical Properties of Oligo[6,6-di(2-thienyl)pentafulvene]s / p69 (0039.jp2)
- 4-7.Synthesis of Oligothienylpentafulvenes Having Hydrogen Atoms on the Terminals / p72 (0041.jp2)
- 4-8.Physical Properties of Oligothienylpentafulvenes Having Hydrogen Atoms on the Terminals / p73 (0041.jp2)
- 4-9.Generation and Characterization of the Anionic Species of Oligothienylpentafulvenes / p78 (0044.jp2)
- 4-10.Experimental Section / p101 (0055.jp2)
- 4-11.References / p115 (0062.jp2)
- Chapter Five:Synthesis and Properties of Cyclic O1igo-6-(2-thienyl)pentafulvenes / p117 (0063.jp2)
- 5-1.Introduction / p117 (0063.jp2)
- 5-2.Synthesis / p120 (0065.jp2)
- 5-3.Physical Properties / p122 (0066.jp2)
- 5-4.Generation and Characterization of Hexaanion of Cyclic Hexakis-6-(2-thienyl) pentafulvene / p129 (0069.jp2)
- 5-5.Experimental Section / p135 (0072.jp2)
- 5-6.References / p137 (0073.jp2)
- Chapter Six:Synthesis and Properties of Oligo(phenylene)pentafulvenes / p139 (0074.jp2)
- 6-1.Introduction / p139 (0074.jp2)
- 6-2.Synthesis of Oligo(m-phenylene)pentafulvenes / p142 (0076.jp2)
- 6-3.Physical Properties of Oligo(m-phenylene)pentafulvenes / p146 (0078.jp2)
- 6-4.Synthesis of Oligo(p-phenylene)pentafulvenes / p152 (0081.jp2)
- 6-5.Physical Properties of Oligo(p-phenylene)pentafulvenes / p154 (0082.jp2)
- 6-6.Experimental Section / p158 (0084.jp2)
- 6-7.References / p172 (0091.jp2)
- List of Publications / p173 (0091.jp2)
- Acknowledgment / p175 (0092.jp2)